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Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.

dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.contributor.advisorMuñoz Acevedo, Juan Carlos
dc.contributor.advisorPabón Gelves, Elizabeth
dc.contributor.authorCardona González, Daniela
dc.date.accessioned2021-06-23T21:04:47Z
dc.date.available2021-06-23T21:04:47Z
dc.date.issued2021
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/79694
dc.descriptionIlustraciones
dc.description.abstractLas redes metal-orgánicas (MOFs) son materiales porosos con aplicaciones en diversas áreas de la industria, tecnología y medio ambiente. El diseño molecular de MOFs ha estado ligado a la naturaleza química del centro metálico, al tipo de ligandos orgánicos, a la relación de la interacción metal-ligando y a su geometría, lo que implica que para garantizar la estabilidad y la supramolecularidad de la red es necesario explorar con ligandos, las condiciones con las cuales se puede obtener una estructura tipo MOF. Se sintetizaron redes metal-orgánicas por medio de una estrategia de ligandos mixtos heteroestructurales; usando los ácidos trans,trans-mucónico (MA) y sulfosuccínico (SSA), acompañados del conector 4,4’-bipiridina (4B) con metales como el Cu (II) y Zn (II). Los compuestos se prepararon por diversas rutas de síntesis a reflujo, solvotermal y agitación y se caracterizaron las propiedades morfológicas, estructurales, térmicas y superficiales por medio de microscopía óptica, FT-IR, XRPD y TGA. Adicionalmente se usó análisis de SC-XRD para la determinación estructural de una nueva estructura 1D de fórmula molecular [Cu(HSSA)(4B)(H2O)2]n·H2O con espacios entre las cadenas con alta polarizabilidad y por lo tanto promisorias para la adsorción selectiva de CO2. Tomado de la fuente)
dc.description.abstractMetal-organic frameworks (MOF) are porous materials with applications in diverse areas like industry, technology and environment. The molecular design of MOFs can be linked to the nature of the metal, organic linker, metal-linker interaction and geometry, implying that is necessary the exploration of synthetic conditions with the linkers to ensure the stability and supramolecularity of the framework. This work presents the synthesis of metal-organic frameworks via heterostructural mixed-linker strategy with trans,trans-muconic acid (MA), sulfosuccinic acid (SSA) and the auxiliary linker 4,4’-bipyridine (4B) coordinated to Cu (II) and Zn(II). The compounds have been synthesized by reflux, solvothermal and agitation conditions and the morphology, structure, thermic and surface area properties were characterized with optic microscopy, FT-IR, XRPD and TGA. SC-XRD analysis was additionally used to determinate the new 1D structure of molecurlar formula [Cu(HSSA)(4B)(H2O)2]n·H2O with free inter-chain spaces, high polarizability and potential selective adsorption properties for CO2 capture. (Tomdo de la fuente)
dc.format.extent146 páginas
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.publisherUniversidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540 - Química y ciencias afines::546 - Química inorgánica
dc.titleSíntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.
dc.typeTrabajo de grado - Maestría
dcterms.audienceEspecializado
dc.type.driverinfo:eu-repo/semantics/masterThesis
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programMedellín - Ciencias - Maestría en Ciencias - Química
dc.contributor.researchgroupCiencia de Materiales Avanzados
dc.description.degreelevelMaestría
dc.description.degreenameMágister en Ciencias - Química
dc.description.researchareaSíntesis de materiales porosos
dc.identifier.instnameUniversidad Nacional de Colombia
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourlhttps://repositorio.unal.edu.co/
dc.publisher.departmentEscuela de química
dc.publisher.facultyFacultad de Ciencias
dc.publisher.placeMedellín, Colombia
dc.publisher.branchUniversidad Nacional de Colombia - Sede Medellín
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.lembMetales - Características físico-químicas
dc.subject.proposalMOF
dc.subject.proposalRedes metal-orgánicas
dc.subject.proposalPorosidad
dc.subject.proposalPorosidad
dc.subject.proposalMetal-organic frameworks
dc.subject.proposalAdsorption
dc.subject.proposalAdsorción
dc.title.translatedSynthesis of heterostructural mixed-ligand metal-organic frameworks
dc.type.coarhttp://purl.org/coar/resource_type/c_bdcc
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
dc.type.redcolhttp://purl.org/redcol/resource_type/TM
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2


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