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Óxidos mixtos CoOx-MnOx sintetizados por autocombustión/MW para la oxidación de tolueno en presencia de agua

dc.rights.licenseAtribución-NoComercial 4.0 Internacional
dc.contributor.advisorMoreno Guaqueta, Sonia
dc.contributor.authorCañón Gómez, Jhonn
dc.date.accessioned2020-08-26T22:34:41Z
dc.date.available2020-08-26T22:34:41Z
dc.date.issued2020-01-31
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/78241
dc.description.abstractLos compuestos orgánicos volátiles (COVs) constituyen uno de los más importantes contaminantes del aire puesto que actúan como agentes precursores del smog fotoquímico, la lluvia ácida y otros compuestos nocivos. La oxidación catalítica se destaca como método de eliminación de COVs gracias a su alta eficiencia y bajos requerimientos energéticos. Dentro de esta estrategia, son muy importantes los catalizadores a base de cobalto y manganeso debido a sus excelentes propiedades redox y a la movilidad de oxígeno dentro de las estructuras. En este trabajo, se sintetizaron catalizadores tipo CoMnMgAl-Ox a través de una autocombustión asistida por microondas y variando la relación molar Co/Mn entre 0 y 1. Los catalizadores fueron caracterizados (DRX, isotermas de adsorción-desorción de N2, HR-TEM y XPS) y evaluados en la oxidación catalítica de tolueno en fase gaseosa diluida y a presión atmosférica. Todos los catalizadores preparados en este trabajo presentaron mayores actividades que sus equivalentes preparados por autocombustión tradicional, demostrando que el uso de microondas en la síntesis, independientemente de la potencia de irradiación, potencia la actividad catalítica de los materiales en la oxidación. Adicionalmente, se encontró que la relación molar Co/Mn = 0.6, es la que da lugar al catalizador más activo, presentando conversiones comparables a las de los catalizadores de metales nobles, lo cual evidencia el efecto cooperativo entre estos metales.
dc.description.abstractVolatile organic compounds (VOCs) are one of the most critical air pollutants since they act as precursor agents for photochemical smog, acid rain, and other harmful compounds. Catalytic oxidation stands out as a method of VOC elimination thanks to its high efficiency and low energy requirements. Within this strategy, the catalysts based on cobalt and manganese stand out due to their excellent redox properties and the mobility of oxygen within the structures. In this work, CoMnMgAl-Ox type catalysts were synthesized through a microwave-assisted self-combustion and varying the Co / Mn molar ratio between 0 and 1. The catalysts were characterized (DRX, N2 adsorption-desorption isotherms, HR-TEM and XPS) and evaluated in the catalytic oxidation of toluene in the diluted gas phase and at atmospheric pressure. All the catalysts prepared in this research presented higher activities than their equivalents prepared by a traditional self-combustion, thus demonstrating that the use of microwaves in the synthesis (regardless of the irradiation power) enhances the catalytic activity in the oxidation. Additionally, it was found that the Co / Mn = 0.6 molar ratio gives rise to the most active catalyst, which has conversions comparable to those of noble metal catalysts.
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dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.rightsDerechos reservados - Universidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.subject.ddc540 - Química y ciencias afines
dc.subject.ddc660 - Ingeniería química
dc.subject.ddc541 - Química física
dc.titleÓxidos mixtos CoOx-MnOx sintetizados por autocombustión/MW para la oxidación de tolueno en presencia de agua
dc.title.alternativeCoOx-MnOx mixed oxides prepared by self-combustión/MW for toluene total oxidation in the presence of water
dc.typeOtro
dc.rights.spaAcceso abierto
dc.description.projectProyecto Hermes 41779 de la Universidad Nacional de Colombia – Sede Bogotá y Proyecto Colciencias código 1115-745-58773.
dc.description.additionalLínea Investigación: Catálisis Heterogénea
dc.type.driverinfo:eu-repo/semantics/other
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ciencias - Maestría en Ciencias - Química
dc.contributor.researchgroupEstado Sólido y Catálisis Ambiental
dc.description.degreelevelMaestría
dc.publisher.departmentDepartamento de Química
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.proposalself-combustion
dc.subject.proposalautocombustión
dc.subject.proposalcompuestos orgánicos volátiles
dc.subject.proposalvolatile organic compounds
dc.subject.proposalmicrowaves
dc.subject.proposalmicroondas
dc.subject.proposalmixed oxides
dc.subject.proposalóxidos mixtos
dc.type.coarhttp://purl.org/coar/resource_type/c_1843
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2


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