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Desarrollo de estructura metal-orgánica soportada sobre policloruro de vinilo y su aplicación en el control de colorantes en medios acuosos

dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.contributor.advisorZea Ramírez, Hugo Ricardo
dc.contributor.advisorSierra Ávila, César Augusto
dc.contributor.authorRojas Forero, Ana Yuri Viviana
dc.date.accessioned2020-11-17T14:40:46Z
dc.date.available2020-11-17T14:40:46Z
dc.date.issued2020-10-28
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/78628
dc.description.abstractTextile industry produces the highest dye discharge worldwide. This industry is one of the most important sectors of economy in Colombia and generates high wastewater amounts. Thus, it´s necessary to develop new and alternative materials and treatments that guarantee the hydric resource quality. The above, considering the inefficiency of the Colombian legislation and the traditional wastewater treatments to accomplish its purpose, causes rise to environmental and human health negative impacts. Metal-organic frameworks (MOFs) are widely known because of their multiple applications, such as gas adsorption, photocatalytic hydrogen production, antibacterial activity and wastewater treatment, etc. However, these fine-powdered materials have not been implemented at large scale as result of their water instability and difficult manipulation. Considering the disadvantages that prevent MOF’s implementation in aqueous media dye-removal applications, herein a PVC/MOF system was developed through physical and chemical modifications in the PVC to support the MOF on its surface employing green chemistry. The PVC is a widely used polymer due to its physical and chemical characteristics and its low-cost production. In the MOF/PVC system it works as the NH2-MIL-53(Al) support. NH2-MIL-53(Al)is a water stable MOF with high surface area and widely used in several applications. The MOF/PVC system synthesis was developed using atom transfer radical polymerization (ATRP) to obtain a PVC-g-poly(methacrylic) acid and subsequently, MOF linkage was achieved, by employing green chemistry on the modified polymer surface on aqueous media. Thereafter, the powder NH2-MIL-53(Al) and the MOF/PVC system were evaluated in the indigo carmine aqueous media removal , achieving up to 89% and 25% of dye reduction, respectively. Finally, we proposed a possible removal mechanism based on the chemical and structural characteristics of the developed system. The MOF/PVC system projects as a wastewater material to treat water with dyes at large scale because of its easily manipulation and recover from the aqueous media characteristic making it moldable according to industry needs.
dc.description.abstractLa industria textil es la mayor aportante de vertimientos con colorantes a nivel mundial. Teniendo en cuenta que en Colombia esta industria representa un sector muy importante de la economía y que su contribución de vertimientos es significativamente alta, se hace necesario el desarrollo de nuevos materiales y tratamientos alternativos que garanticen la calidad del recurso hídrico. Lo anterior, considerando que la legislación ambiental colombiana y los tratamientos tradicionales de aguas residuales resultan ineficaces en el cumplimiento de este propósito generando así impactos negativos, tanto ambientales como de salud pública. Las estructuras metal-orgánicas (MOF) son ampliamente conocidas a causa de sus múltiples aplicaciones, tales como adsorción de gases, producción fotocatalítica de hidrógeno, actividad antibacterial y tratamiento de aguas, entre otras. A pesar de esto, no se ha implementado el uso de este tipo de materiales a gran escala debido a que, por un lado, son inestables en medios acuosos y, por otro lado, su estado físico consiste en un polvo muy fino, lo cual dificulta su manipulación. Teniendo en cuenta las desventajas previamente mencionadas que impiden la implementación de los MOF para la remoción de colorantes en medios acuosos, en el presente trabajo se desarrolló un sistema MOF/PVC mediante modificaciones físicas y químicas del policloruro de vinilo (PVC) para soportar el MOF en su superficie. El PVC, material ampliamente empleado en la industria debido a sus características físicas, químicas y su bajo costo, actúa en el sistema MOF/PVC como soporte del MOF estable en agua, NH2-MIL-53(Al), que presenta gran área superficial y gran variedad de aplicaciones. La síntesis del sistema MOF/PVC se desarrolló mediante una polimerización radicalaria por transferencia de átomo (ATRP, por sus siglas en inglés) para obtener PVC-g-ácido poli(metacrílico), y el posterior anclaje del MOF siguiendo una metodología verde sobre la superficie modificada del polímero en medio acuoso. Enseguida, se evaluó el NH2-MIL-53(Al) en polvo y el sistema PVC/MOF desarrollado, en la remoción de índigo carmín en medio acuoso, alcanzando una reducción de hasta un 89% y un 25% en la concentración del colorante en el medio acuoso, respectivamente. Finalmente, se propuso un posible mecanismo de adsorción del colorante, con base en las características químicas y estructurales del sistema desarrollado. El sistema MOF/PVC se proyecta como un material para el tratamiento de aguas contaminadas con colorantes a gran escala, puesto que puede ser fácilmente manipulado y recuperado del medio acuoso y, de esta manera moldearse de acuerdo a las necesidades de la industria.
dc.format.extent91
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.rightsDerechos reservados - Universidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc660 - Ingeniería química
dc.titleDesarrollo de estructura metal-orgánica soportada sobre policloruro de vinilo y su aplicación en el control de colorantes en medios acuosos
dc.typeOtro
dc.rights.spaAcceso abierto
dc.description.additionalLínea de investigación: Ciencia de materiales
dc.type.driverinfo:eu-repo/semantics/other
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.contributor.researchgroupGrupo de Investigación en Materiales, Catálisis y Medio Ambiente
dc.description.degreelevelMaestría
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.proposalEstructura metal-orgánica
dc.subject.proposalMetal-organic framework
dc.subject.proposalMOF
dc.subject.proposalMOF
dc.subject.proposalNH2-MIL-53(Al)
dc.subject.proposalNH2-MIL-53(Al)
dc.subject.proposalpolicloruro de vinilo
dc.subject.proposalpolyvinyl chloride
dc.subject.proposalPVC
dc.subject.proposalPVC
dc.subject.proposalíndigo carmín
dc.subject.proposalindigo carmine
dc.type.coarhttp://purl.org/coar/resource_type/c_1843
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2


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