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Alternativas de Aprovechamiento del Glicerol

dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.contributor.advisorRomero Malagón, Eduard Ricardo
dc.contributor.authorUsme Contreras, Juan Diego
dc.date.accessioned2021-01-27T19:56:36Z
dc.date.available2021-01-27T19:56:36Z
dc.date.issued2020-08-10
dc.identifier.citationUsme , C., Juan D. (2020) Alternativas de Aprovechamiento del Glicerol. Universidad Nacional de Colombia - Sede Bogotá, Bogotá Colombia.
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/78946
dc.description.abstractGlycerol by-product of biodiesel manufacturing has increased consequence of the high use of biofuels on the last 30 years. Likewise, Colombia has 12 biodiesel plants which produce more than 480 KT of biofuel per year, and according to the esterification reaction proportion, raw glycerin occupies 10% such all production. Because this scenario, the internationally manufacture of USP glycerol from propene was suspended, instead to produce epichlorohydrin (epoxy resins precursor) from glycerol. Along with this glycerol derivative, the reaction conditions, and applications of value chemicals such as glycerin ethers and esters (GTBE and acetins), methanol, methane, acrolein, 1,3-propanediol, tartronic acid, glyceric acid, mesoxalic acid, dihydroxyacetone and glycerol carbonate are explored. Glycerol derivatives were categorized into three groups according to their level of industrial development, country background, economic aspects (value per Kg, market size, amount estimate investment for the projected application) to choose industrial potential reactions satisfy green chemistry principles: esterification with 5% sulfonated carbonized at 115°C, 1 h, with 4:1 AcOH/glycerol and 1:1 Ac2O/glycerol for 30 with 100% triacetin yield; FePO4-mediated dehydration at 280°C, 5 h, 0.40 glycerol/H2O with 92% acrolein yield and transesterification-carbonylation with 0.10 CaO/glycerol at 75°C, 90 min, 1:1 DMC to produce 95% glycerol carbonate yield.
dc.description.abstractEn los últimos 30 años como consecuencia del crecimiento del uso de biocombustibles. Colombia posee 12 plantas La producción de glicerol subproducto de la fabricación de biodiesel se ha incrementado de biodiesel que producen más de 480 KT anuales del biocombustible y de acuerdo con la proporción de la reacción de esterificación, la glicerina cruda ocupa el 10% de la totalidad de la producción. Dado que no es posible dar un uso a tal cantidad de glicerina, a pesar de sus diversas aplicaciones en este documento se hace énfasis en analizar las investigaciones realizadas en relación con las síntesis de compuestos derivados del glicerol que tienen aplicaciones con valor comercial como los éteres y ésteres de glicerina (GTBE y acetinas), metanol, metano, acroleína, 1,3-propanodiol ácido tartrónico, ácido glicérico, ácido mesoxálico, dihidroxiacetona y carbonato de glicerol. Se categorizaron los derivados del glicerol en tres grupos según su nivel de explotación industrial, los antecedentes de uso en el país, los aspectos económicos (valor/kg del tamaño del mercado, la inversión estimada y la magnitud económica de la aplicación proyectada) para la elección de las siguientes reacciones químicas con potencial industrial incluyendo criterios de la química verde: La esterificación con 5% carbonizado sulfonado a 115°C, 1 h, con 4:1 AcOH/glicerol y 1:1 Ac2O/glicerol por 30 min obteniendo 100% de triacetina; La deshidratación con FePO4 a 280°C, 5 h, 0,40 glicerol/H2O para obtener 92% de acroleína y, La transesterificación-carbonilación con 0,10 CaO/glicerol a 75°C, 90 min, 3:1 DMC/glicerol logrando 95% de carbonato de glicerol..
dc.format.extent114
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.rightsDerechos reservados - Universidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.ddc540 - Química y ciencias afines
dc.titleAlternativas de Aprovechamiento del Glicerol
dc.title.alternativeGlycerol Utilization Alternatives
dc.typeOtro
dc.rights.spaAcceso abierto
dc.description.additionalLínea de investigación: Materiales y energía Trabajo aceptado en agosto de 2020 por el programa curricular del departamento de Química, Facultad de Ciencias, sede Bogotá. Realización de Socialización de este Trabajo Final de Maestría en Ciencias Química el 23 de Octubre 2020 aprobatorio.
dc.type.driverinfo:eu-repo/semantics/other
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ciencias - Maestría en Ciencias - Química
dc.contributor.researchgroupLABORATORIO DE INVESTIGACIÓN EN COMBUSTIBLES Y ENERGÍA
dc.description.degreelevelMaestría
dc.publisher.departmentDepartamento de Química
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.proposalDerivados del glicerol
dc.subject.proposalGlycerol derivatives
dc.subject.proposalGlycerol valorization
dc.subject.proposalValorización de la glicerina
dc.subject.proposalAcetinas
dc.subject.proposalAcetins
dc.subject.proposalCarbonato de glicerol
dc.subject.proposalGlycerol carbonate
dc.subject.proposalAcroleína
dc.subject.proposalacrolein
dc.type.coarhttp://purl.org/coar/resource_type/c_1843
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2


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