Mostrar el registro sencillo del documento

Understanding bio-oil droplets microexplosions in oxyfuel combustion.

dc.rights.licenseReconocimiento 4.0 Internacional
dc.contributor.advisorChejne Jana, Farid
dc.contributor.advisorAmell Arrieta, Andrés
dc.contributor.authorOrdoñez Loza, Javier Alonso
dc.date.accessioned2021-10-14T19:33:00Z
dc.date.available2021-10-14T19:33:00Z
dc.date.issued2021-06-21
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/80555
dc.descriptionilustraciones, diagramas, tablas
dc.description.abstractSugarcane bagasse bio-oil is a low calorific fuel produced by pyrolysis of cane bagasse in a nitrogen atmosphere and can be considered as a future alternative fuel. In this doctoral thesis, a detailed characterization of the bio-oil was developed, and the effect of carbon dioxide on char formation during thermal decomposition was evaluated. The kinetics was also analyzed, and decomposition stages were proposed. Likewise, bio-oil droplet evaporation experiments were carried out and allowed to identify the nature of the phenomenon of micro-explosions and its relationship with the formation of microbubbles, to complement the work, a novel model to predict micro-explosions were developed offering the possibility of understanding the phenomenon of micro-explosion formation from a collection of physicochemical events that begin with the nucleation, coalescence, and explosion of microbubbles within the drop.
dc.description.abstractEl bio-aceite de bagazo de caña es un combustible de bajo poder calorífico producido por la pirólisis de bagazo de caña en atmósfera de nitrógeno, y puede considerarse como un futuro combustible alternativo. En esta tesis una caracterización detallada del bio-aceite fue desarrollada, y se evaluó el efecto del dióxido de carbono en la formación de carbonizado durante la descomposición térmica. También se analizó la cinética y etapas de descomposición fueron propuestas. Así mismo experimentos de evaporación de gotas de bio-aceite fueron realizados y permitieron identificar la naturaleza del fenómeno de las micro-explosiones y su relación con la formación de microburbujas, para complementar el trabajo un novedoso modelo para predecir las micro-explosiones fue desarrollado ofreciendo la posibilidad de entender el fenómeno de formación de micro-explosiones a partir de una colección de eventos fisicoquímicos que comienzan con la nucleación, coalescencia y explosione de microburbujas dentro de la gota. (Texto tomado de la fuente)
dc.format.extentxix, 120 páginas
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540 - Química y ciencias afines
dc.subject.otherAceite de bagazo de caña
dc.titleUnderstanding bio-oil droplets microexplosions in oxyfuel combustion.
dc.typeTrabajo de grado - Doctorado
dc.type.driverinfo:eu-repo/semantics/doctoralThesis
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programMedellín - Minas - Doctorado en Ingeniería - Sistemas Energéticos
dc.contributor.researchgroupTermodinámica Aplicada y Energías Alternativas
dc.description.degreelevelDoctorado
dc.description.degreenameDoctor en Ingeniería
dc.description.researchareaSistemas Energéticos
dc.identifier.instnameUniversidad Nacional de Colombia
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourlhttps://repositorio.unal.edu.co/
dc.publisher.departmentDepartamento de Procesos y Energía
dc.publisher.facultyFacultad de Minas
dc.publisher.placeMedellín, Colombia
dc.publisher.branchUniversidad Nacional de Colombia - Sede Medellín
dc.relation.references[1] R. Calabria, F. Chiariello, P. Massoli, Combustion fundamentals of pyrolysis oil based fuels, Exp. Therm. Fluid Sci. 31 (2007) 413–420. https://doi.org/10.1016/j.expthermflusci.2006.04.010.
dc.relation.references[2] M. Garcia-Perez, P. Lappas, P. Hughes, L. Dell, A. Chaala, D. Kretschmer, C. Roy, Evaporation and combustion characteristics of biomass vacuum pyrolysis oils, IFRF Combust. J. 200601 (2006) 1–27.
dc.relation.references[3] Á. Muelas, M.S. Callén, R. Murillo, J. Ballester, Production and droplet combustion characteristics of waste tire pyrolysis oil, Fuel Process. Technol. 196 (2019). https://doi.org/10.1016/j.fuproc.2019.106149.
dc.relation.references[4] C. Branca, C. Di Blasi, Combustion kinetics of secondary biomass chars in the kinetic regime, Energy and Fuels. 24 (2010) 5741–5750. https://doi.org/10.1021/ef100952x.
dc.relation.references[5] Z. Xiong, S.S.A. Syed-hassan, X. Hu, J. Guo, J. Qiu, X. Zhao, Pyrolysis of the aromatic-poor and aromatic-rich fractions of bio-oil : Characterization of coke structure and elucidation of coke formation mechanism, Appl. Energy. 239 (2019) 981–990. https://doi.org/10.1016/j.apenergy.2019.01.253.
dc.relation.references[6] P. Eng, D. Scarpete, Diesel-water emulsion, an alternative fuel to reduce diesel engine emissions. A review, Mach. Technol. Mater. (2013) 7–10.
dc.relation.references[7] C.Y. Hsuan, S.S. Hou, Y.L. Wang, T.H. Lin, Water-In-Oil emulsion as boiler fuel for Reduced NOx emissions and improved energy saving, Energies. 12 (2019) 1–14. https://doi.org/10.3390/en12061002.
dc.relation.references[8] M.L. Botero, Y. Huang, D.L. Zhu, A. Molina, C.K. Law, Synergistic combustion of droplets of ethanol, diesel and biodiesel mixtures, Fuel. 94 (2012) 342–347. https://doi.org/10.1016/j.fuel.2011.10.049.
dc.relation.references[9] C.K. Law, C.H. Lee, N. Srinivasan, Combustion characteristics of water-in-oil emulsion droplets, Combust. Flame. 37 (1980) 125–143. https://doi.org/10.1016/0010-2180(80)90080-2.
dc.relation.references[10] R.H. C. R. Shaddix, D, Combustion Properties of Biomass Flash Pyrolysis Oils : Final Project Report, 1999. https://doi.org/10.2172/5983.
dc.relation.references[11] C.R. Shaddix, S.P. Huey, Combustion characteristics of fast pyrolysis oils derived from hybrid poplar, Dev. Thermochem. Biomass Convers. (1997) 1630.
dc.relation.references[12] M.J. Wornat, B.G. Porter, N.Y.C. Yang, Single Droplet Combustion of Biomass Pyrolysis Oils, Energy & Fuels. 8 (1994) 1131–1142. https://doi.org/10.1021/Ef00047a018.
dc.relation.references[13] C. Branca, C. Di Blasi, Multistep mechanism for the devolatilization of biomass fast pyrolysis oils, Ind. Eng. Chem. Res. 45 (2006) 5891–5899. https://doi.org/10.1021/ie060161x.
dc.relation.references[14] F. Stankovikj, A.G. McDonald, G.L. Helms, M. Garcia-Perez, Quantification of Bio-Oil Functional Groups and Evidences of the Presence of Pyrolytic Humins, Energy and Fuels. 30 (2016) 6505–6524. https://doi.org/10.1021/acs.energyfuels.6b01242.
dc.relation.references[15] D.C.K. Rao, S. Syam, S. Karmakar, R. Joarder, Experimental investigations on nucleation , bubble growth , and micro- explosion characteristics during the combustion of ethanol / Jet A-1 fuel droplets, Exp. Therm. Fluid Sci. 89 (2017) 284–294. https://doi.org/10.1016/j.expthermflusci.2017.08.025.
dc.relation.references[16] A.R. Teixeira, K.G. Mooney, J.S. Kruger, C.L. Williams, W.J. Suszynski, L.D. Schmidt, D.P. Schmidt, P.J. Dauenhauer, Aerosol generation by reactive boiling ejection of molten cellulose, Energy Environ. Sci. 4 (2011) 4306–4321. https://doi.org/10.1039/c1ee01876k.
dc.relation.references[17] J.H. Han, C.D.A.E. Han, Bubble Nucleation in Polymeric Liquids . 11 . Theoretical Considerations, J. Polym. Sci. B Polym. Phys. 28 (1990) 743–761. https://doi.org/10.1002/polb.1990.090280510.
dc.relation.references[18] J.L. Katz, Bubble Nucleation in Liquids, AIChE J. 21 (1975) 833–848. https://doi.org/10.1002/aic.690210502.
dc.relation.references[19] D.C. Venerus, N. Yala, B. Bernstein, Analysis of diffusion-induced bubble growth in viscoelastic liquids, J. Non-Newtonian Fluid Mech. 75 (1998) 55–75. https://doi.org/10.1016/S0377-0257(97)00076-1.
dc.relation.references[20] H. Schulz, Short history and present trends of Fischer – Tropsch synthesis, 186 (1999) 3–12. [21] B.H. Davis, Overview of reactors for liquid phase Fischer – Tropsch synthesis, 71 (2002) 249–300.
dc.relation.references[21] B.H. Davis, Overview of reactors for liquid phase Fischer – Tropsch synthesis, 71 (2002) 249–300.
dc.relation.references[22] Y. Cheng, Y. Shen, D. Liu, J. Xu, Y. Sui, Numerical analysis of bubble bursting at the liquid surface by wave propagation, Int. J. Therm. Sci. 152 (2020) 106341. https://doi.org/10.1016/j.ijthermalsci.2020.106341.
dc.relation.references[23] B.Y. Ni, A.M. Zhang, G.X. Wu, Simulation of a fully submerged bubble bursting through a free surface, Eur. J. Mech. B/Fluids. 55 (2016) 1–14. https://doi.org/10.1016/j.euromechflu.2015.08.001.
dc.relation.references[24] K.M. Butler, A Numerical Model for Combustion of Bubbling Thermoplastic Materials in Microgravity, 2002. https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=861181.
dc.relation.references[25] H.-Y. Kwak, Y.W. Kim, Homogeneous nucleation and macroscopic growth of gas bubble in organic solutions, Int. J. Heat Mass Transf. 41 (1998) 757–767. https://doi.org/10.1016/S0017-9310(97)00182-8.
dc.relation.references[26] L. Hao, Analysis of bubble growth and motion dynamics in superheated liquid during flash evaporation, Int. J. Heat Mass Transf. 151 (2020) 119356. https://doi.org/10.1016/j.ijheatmasstransfer.2020.119356.
dc.relation.references[27] S. Hoon, C. Park, J. Lee, B. Lee, A Simple Parameterization for the Rising Velocity of Bubbles in a Liquid Pool, Nucl. Eng. Technol. 49 (2017) 692–699. https://doi.org/10.1016/j.net.2016.12.006.
dc.relation.references[28] F. Stankovikj, M. Garcia-perez, TG-FTIR Method for the Characterization of Bio-oils in Chemical Families, Energy & Fuels. 30 (2017) 1689–1701. https://doi.org/10.1021/acs.energyfuels.6b03132.
dc.relation.references[29] F. Stankovikj, C.-C. Tran, S. Kaliaguine, M. V. Olarte, M. Garcia-Perez, Evolution of Functional Groups during Pyrolysis Oil Upgrading, Energy & Fuels. (2017) acs.energyfuels.7b01251. https://doi.org/10.1021/acs.energyfuels.7b01251.
dc.relation.references[30] A.R. Teixeira, R.J. Hermann, J.S. Kruger, W.J. Suszynski, L.D. Schmidt, D.P. Schmidt, P.J. Dauenhauer, Microexplosions in the upgrading of biomass-derived pyrolysis oils and the effects of simple fuel processing, ACS Sustain. Chem. Eng. 1 (2013) 341–348. https://doi.org/10.1021/sc300148b.
dc.relation.references[31] G. Lu, X. Wang, W. Yan, International Journal of Heat and Mass Transfer Nucleate boiling inside small evaporating droplets : An experimental and numerical study, Int. J. Heat Mass Transf. 108 (2017) 2253–2261. https://doi.org/10.1016/j.ijheatmasstransfer.2017.01.081.
dc.relation.references[32] D. Yepes, F. Chejne, Gasificación de biomasa residual en el sector floricultor , caso : Oriente Antioqueño Gasification of waste biomass in the flower industry , case : Eastern Antioquia, ION. 25 (2012) 49–55.
dc.relation.references[33] G. Marrugo, C.F. Valdés, F. Chejne, Biochar Gasification: An Experimental Study on Colombian Agroindustrial Biomass Residues in a Fluidized Bed, Energy & Fuels. 31 (2017) 9408–9421. https://doi.org/10.1021/acs.energyfuels.7b00665.
dc.relation.references[34] Z. Xiong, Y. Wang, S.S.A. Syed-Hassan, X. Hu, H. Han, S. Su, K. Xu, L. Jiang, J. Guo, E.E.S. Berthold, S. Hu, J. Xiang, Effects of heating rate on the evolution of bio-oil during its pyrolysis, Energy Convers. Manag. 163 (2018) 420–427. https://doi.org/10.1016/j.enconman.2018.02.078.
dc.relation.references[35] S.I. Yang, M.S. Wu, T.C. Hsu, Spray combustion characteristics of kerosene/bio-oil part I: Experimental study, Energy. 119 (2017) 26–36. https://doi.org/10.1016/j.energy.2016.12.062.
dc.relation.references[36] J. Lehto, A. Oasmaa, Y. Solantausta, M. Kytö, D. Chiaramonti, Fuel oil quality and combustion of fast pyrolysis bio-oils, VTT Publ. (2013) 79. https://doi.org/10.1016/j.apenergy.2013.11.040.
dc.relation.references[37] W.L.H. Hallett, N.A. Clark, A model for the evaporation of biomass pyrolysis oil droplets, 85 (2006) 532–544. https://doi.org/10.1016/j.fuel.2005.08.006.
dc.relation.references[38] D.E. Spiel, The number and size of jet drops produced by air bubbles bursting on Understanding bio-oil droplets microexplosions in oxyfuel combustion a fresh water surface, J. Geophys. Res. 99 (1994) 10289–10296. https://doi.org/10.1029/94JC00382.
dc.relation.references[39] R.P.B. Ramachandran, G. Van Rossum, W.P.M. Van Swaaij, S.R.A. Kersten, Evaporation of biomass fast pyrolysis oil: Evaluation of char formation, Environ. Prog. Sustain. Energy. (2009). https://doi.org/10.1002/ep.10388.
dc.relation.references[40] W. Chaiwat, I. Hasegawa, T. Tani, K. Sunagawa, K. Mae, Analysis of cross-linking behavior during pyrolysis of cellulose for elucidating reaction pathway, Energy and Fuels. 23 (2009) 5765–5772. https://doi.org/10.1021/ef900674b. [41] M. Garcia-Perez, A. Chaala, H. Pakdel, D. Kretschmer, C. Roy, Characterization of bio-oils in chemical families, Biomass and Bioenergy. 31 (2007) 222–242. https://doi.org/10.1016/j.biombioe.2006.02.006. [42] A.G.M.T. Siriwardhana, Aging and Stabilization of Pyrolitic Bio-Oils and Model Compounds, The University of Western Ontario, 2013. http://ir.lib.uwo.ca/cgi/viewcontent.cgi?article=3005&context=etd.
dc.relation.references[40] W. Chaiwat, I. Hasegawa, T. Tani, K. Sunagawa, K. Mae, Analysis of cross-linking behavior during pyrolysis of cellulose for elucidating reaction pathway, Energy and Fuels. 23 (2009) 5765–5772. https://doi.org/10.1021/ef900674b. [41] M. Garcia-Perez, A. Chaala, H. Pakdel, D. Kretschmer, C. Roy, Characterization of bio-oils in chemical families, Biomass and Bioenergy. 31 (2007) 222–242. https://doi.org/10.1016/j.biombioe.2006.02.006. [42] A.G.M.T. Siriwardhana, Aging and Stabilization of Pyrolitic Bio-Oils and Model Compounds, The University of Western Ontario, 2013. http://ir.lib.uwo.ca/cgi/viewcontent.cgi?article=3005&context=etd.
dc.relation.references[40] W. Chaiwat, I. Hasegawa, T. Tani, K. Sunagawa, K. Mae, Analysis of cross-linking behavior during pyrolysis of cellulose for elucidating reaction pathway, Energy and Fuels. 23 (2009) 5765–5772. https://doi.org/10.1021/ef900674b.
dc.relation.references[41] M. Garcia-Perez, A. Chaala, H. Pakdel, D. Kretschmer, C. Roy, Characterization of bio-oils in chemical families, Biomass and Bioenergy. 31 (2007) 222–242. https://doi.org/10.1016/j.biombioe.2006.02.006.
dc.relation.references[42] A.G.M.T. Siriwardhana, Aging and Stabilization of Pyrolitic Bio-Oils and Model Compounds, The University of Western Ontario, 2013. http://ir.lib.uwo.ca/cgi/viewcontent.cgi?article=3005&context=etd.
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.lembCombustibles
dc.subject.lembTransformation of waste
dc.subject.lembTransformación de residuos
dc.subject.proposalPyrolysis
dc.subject.proposalCO2
dc.subject.proposalChar reactivity
dc.subject.proposalDroplet evaporation
dc.subject.proposalBio-oil
dc.subject.proposalChar
dc.subject.proposalBio-aceite
dc.subject.proposalPirólisis
dc.subject.proposalCarbón
dc.subject.proposalReactividad del carbón
dc.subject.proposalEvaporación de gotas
dc.title.translatedComprensiónde las micro explosiones de gotas de bio-aceite en condiciones de oxicombustión.
dc.type.coarhttp://purl.org/coar/resource_type/c_db06
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
dc.type.redcolhttp://purl.org/redcol/resource_type/TD
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2
oaire.fundernameMinciencias
dcterms.audience.professionaldevelopmentInvestigadores


Archivos en el documento

Thumbnail
Nombre:
1085280963.2021.pdf
Tamaño:
3.452Mb
Formato:
PDF
Descripción:
Tesis de Maestría en Ingeniería ...
Descargar

Este documento aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del documento

Reconocimiento 4.0 InternacionalEsta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial 4.0.Este documento ha sido depositado por parte de el(los) autor(es) bajo la siguiente constancia de depósito