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Contribución de grupos polares a las propiedades termodinámicas de soluciones acuosas de aminoalcoholes

dc.rights.licenseReconocimiento 4.0 Internacional
dc.contributor.advisorRomero Isaza, Carmen María
dc.contributor.authorCruz Alvarado, Yadhi Patricia
dc.date.accessioned2022-08-25T19:35:59Z
dc.date.available2022-08-25T19:35:59Z
dc.date.issued2021
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/82113
dc.descriptionilustraciones, graficas
dc.description.abstractEn la presente investigación se presenta propiedades entálpicas, volumétricas y superficiales de mezclas de 3-amino-1-propanol, (RS)-1-amino-2-propanol ó (RS)-2-amino-1-propanol, 3-amino-1,2-propanodiol y 1,3-diamino-2-propano, con agua y en función de la temperatura. Los solutos seleccionados, sustituidos en diferentes posiciones con grupos hidroxilo y amino, permitieron evaluar el efecto de la contribución de los grupos polares en las interacciones moleculares en solución acuosa. Las entalpías de dilución se determinaron empleando microcalorimetría de flujo a 298,15 K, mientras que a partir de la teoría de McMillan-Mayer se calcularon los coeficientes de interacción entre pares de moléculas, por lo que se aplicó un esquema de contribución de grupo. A su vez, las propiedades volumétricas se encontraron a partir de medidas de densidad y velocidad del sonido de soluciones diluidas en función de la composición y la temperatura en el rango de 293,15 a 308,15 K; con las cuales se analizó el proceso de hidratación y se calcularon los números de hidratación. La tensión superficial de las mezclas se evaluó por el método de volumen de gota pendiente en función de la temperatura (293,15 a 308,15 K) y en todo el rango de composición, obteniendo parámetros de hidrofobicidad, coeficientes de actividad y propiedades de superficie. Los resultados fueron analizados en términos de las interacciones moleculares soluto-agua y soluto-soluto, además del proceso de hidratación. Se encontró que la contribución de los grupos polares no es aditiva, además de una notable diferencia entre la contribución de cada uno de los grupos a las propiedades termodinámicas evaluadas. (Texto tomado de la fuente)
dc.description.abstractThis research presents enthalpic, volumetric and surface properties of mixtures of 3-amino-1-propanol, (RS) -1-amino-2-propanol or (RS) -2-amino-1-propanol, 3-amino -1,2-propanediol and 1,3-diamino-2-propane, with water and as a function of temperature. The selected solutes, substituted in different positions with hydroxyl and amino groups, allowed to evaluate the effect of the contribution of the polar groups in the molecular interactions in aqueous solution. The dilution enthalpies, were determined using flow microcalorimetry at 298.15 K and from McMillan's theory the interaction coefficients between pairs of molecules were calculated and a group contribution scheme was applied. In addition, the volumetric properties were found from measurements of density and speed of sound, in dilute solutions as a function with composition and temperature in the range of 293.15 to 308.15 K; with which the hydration process was analyzed and the hydration numbers were calculated. The surface tension of the mixtures was evaluated by the volume pendant drop method, as a function of temperature (293.15 to 308.15 K) and throughout the composition range; obtaining hydrophobicity parameters, activity coefficients and surface properties. The results were analyzed in terms of solute-water and solute-solute molecular interactions, in addition to the hydration process. In turn, it was found that the contribution of the polar groups is not additive, in addition to a notable difference between the contribution of each of the groups to the evaluated thermodynamic properties.
dc.format.extentxxv, 179 páginas
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.publisherUniversidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.ddc540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materiales
dc.titleContribución de grupos polares a las propiedades termodinámicas de soluciones acuosas de aminoalcoholes
dc.typeTrabajo de grado - Doctorado
dc.type.driverinfo:eu-repo/semantics/doctoralThesis
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ciencias - Doctorado en Ciencias - Química
dc.contributor.researchgroupTermodinámica Clásica
dc.description.degreelevelDoctorado
dc.description.degreenameDoctor en Ciencias - Química
dc.description.researchareaEstudio Fisicoquímico de Interacciones en Solución
dc.identifier.instnameUniversidad Nacional de Colombia
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourlhttps://repositorio.unal.edu.co/
dc.publisher.departmentDepartamento de Química
dc.publisher.facultyFacultad de Ciencias
dc.publisher.placeBogotá, Colombia
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
dc.relation.indexedRedCol
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.lembSOLUCIONES (QUIMICA)
dc.subject.lembSolution (chemistry)
dc.subject.proposalAminoalcoholes
dc.subject.proposalEntalpía de dilución
dc.subject.proposalVolumen molar parcial
dc.subject.proposalCompresibilidad molar parcial
dc.subject.proposalTensión superficial
dc.subject.proposalInteracciones moleculares
dc.subject.proposalContribución de grupos polares
dc.subject.proposalAmino alcohols
dc.subject.proposalDilution enthalpy
dc.subject.proposalPartial molar volume
dc.subject.proposalPartial molar compressibility
dc.subject.proposalSurface tension
dc.subject.proposalMolecular interactions
dc.subject.proposalContribution of polar groups
dc.title.translatedContribution of polar groups to the thermodynamic properties of aqueous solutions of amino alcohols
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dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
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oaire.accessrightshttp://purl.org/coar/access_right/c_abf2
oaire.awardtitleEstudio fisicoquímico de interacciones en solución. Fase III
oaire.fundernameDIEB
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