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Evaluación de la resistencia a la corrosión de recubrimientos de TiB2 depositados sobre Ti y Ti-6Al-4V obtenidos mediante la técnica de láser cladding coaxial

dc.rights.licenseReconocimiento 4.0 Internacional
dc.contributor.advisorAngarita Moncaleano, Irma Inirida
dc.contributor.advisorOlaya Florez, Jhon Jairo
dc.contributor.authorAgredo Diaz, Dayi Giberto
dc.date.accessioned2023-01-17T16:33:04Z
dc.date.available2023-01-17T16:33:04Z
dc.date.issued2022
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/82981
dc.descriptionilstraciones, fotografías, graficas
dc.description.abstractEl titanio es un material altamente utilizado en la industria, condición ligada a sus buenas propiedades, sin duda alguna esto ofrece ventajas importantes con respecto a materiales como el acero; es así que las industrias de mayor demanda son la aeronáutica, medica, industria armamentista e incluso en el ámbito deportivo. En esta investigación se sintetizan recubrimientos metal-cerámica (60% wt de Ti+ 40% wt de TiB2) por la técnica de láser cladding coaxial sobre sustratos de Ti grado 2 y Ti-6Al-4V a diferentes niveles de energía (600, 900 y 1000 W) y se evalúa su comportamiento electroquímico en una solución de NaCl al 3.5% y a alta temperatura. Se caracteriza el material por microscopia electrónica de barrido, la evaluación electroquímica se hace por medio de espectroscopia de impedancia y polarización tafel, su estructura se evalúa por difracción de rayos X. La corrosión a alta temperatura es evaluada por medio de la técnica de oxidación cíclica. A nivel electroquímico los resultados muestran que los recubrimientos modifican la respuesta electroquímica del sistema, brindando protección sobre la superficie del material, lo cual está asociado a la formación de una capa protectora sobre la superficie del material (formación de compuestos de TiB, TiB2, TiO2; en la corrosión a alta temperatura se encuentra reducción de la degradación del material recubierto a diferencia del material sin recubrimiento, evidenciando la formación de compuestos principalmente constituidos por TiO2 (Texto tomado de la fuente).
dc.description.abstractTitanium is a highly used material in the industry, a condition linked to its good properties, without a doubt this offers important advantages with respect to materials such as steel; Thus, the industries with the greatest demand are aeronautics, medicine, the arms industry and even sports. In this research, metal-ceramic coatings (60% wt Ti+ 40% wt TiB2) are synthesized using the coaxial laser cladding technique on Ti grade 2 and Ti-6Al-4V substrates at different energy levels (600, 900 and 1000 W) and its electrochemical behavior is evaluated in a 3.5% NaCl solution and at high temperature. The material is characterized by scanning electron microscopy, the electrochemical evaluation is done by means of impedance spectroscopy and tafel polarization, its structure is evaluated by X-ray diffraction. Corrosion at high temperature is evaluated using of the cyclic oxidation technique. At an electrochemical level, the results show that the coatings modify the electrochemical response of the system, providing protection on the surface of the material, which is associated with the formation of a protective layer on the surface of the material (formation of compounds of TiB, TiB2, TiO2; in high-temperature corrosion, a reduction in the degradation of the coated material is found, unlike the uncoated material, evidencing the formation of compounds mainly constituted by TiO2.
dc.format.extentxvii, 107 páginas
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.publisherUniversidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.ddc660 - Ingeniería química::669 - Metalurgia
dc.titleEvaluación de la resistencia a la corrosión de recubrimientos de TiB2 depositados sobre Ti y Ti-6Al-4V obtenidos mediante la técnica de láser cladding coaxial
dc.typeTrabajo de grado - Maestría
dc.type.driverinfo:eu-repo/semantics/masterThesis
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ingeniería - Maestría en Ingeniería - Materiales y Procesos
dc.contributor.researchgroupGrupo de Investigación Afis (Análisis de Fallas, Integridad y Superficies)
dc.contributor.researchgroupGrupo de Investigación en Corrosión, Tribologia y Energía
dc.description.degreelevelMaestría
dc.description.degreenameMagíster en Ingeniería - Materiales y Procesos
dc.description.researchareaIngenieria de superficies
dc.identifier.instnameUniversidad Nacional de Colombia
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourlhttps://repositorio.unal.edu.co/
dc.publisher.facultyFacultad de Ingeniería
dc.publisher.placeBogotá, Colombia
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.lembTITANIO
dc.subject.lembTitanium
dc.subject.lembMATERIALES RESISTENTES A LA CORROSION
dc.subject.lembCorrosion resistant materials
dc.subject.proposalTi-6Al-4V
dc.subject.proposalLáser cladding coaxial
dc.subject.proposalRecubrimientos cerámicos por láser
dc.subject.proposalCorrosión electroquímica
dc.subject.proposalOxidación cíclica
dc.subject.proposalTi-6Al-4V
dc.subject.proposalCoaxial Laser Cladding
dc.subject.proposalLaser Ceramic Coatings
dc.subject.proposalElectrochemical Corrosion
dc.subject.proposalCyclic Oxidation
dc.title.translatedEvaluation of the corrosion resistance of TiB2 coatings deposited on Ti and Ti-6Al-4V obtained using coaxial laser cladding technique
dc.type.coarhttp://purl.org/coar/resource_type/c_bdcc
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
dc.type.redcolhttp://purl.org/redcol/resource_type/TM
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2
dcterms.audience.professionaldevelopmentEstudiantes
dcterms.audience.professionaldevelopmentInvestigadores
dcterms.audience.professionaldevelopmentPúblico general
dc.contributor.orcidAgredo Diaz, Dayi Gilberto [0000-0003-2830-3022]
dc.contributor.googlescholarhttps://scholar.google.es/citations?user=SkA2vycAAAAJ&hl=es


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