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Evaluación de métodos de tratamiento para la degradación de colorante en el agua residual de la industria de las curtiembres
dc.rights.license | Atribución-NoComercial-CompartirIgual 4.0 Internacional |
dc.contributor.advisor | Dobrosz-Gómez, Izabela |
dc.contributor.advisor | Gómez García, Miguel Ángel |
dc.contributor.author | Gómez Rodríguez, Carlos Andrés |
dc.date.accessioned | 2023-02-06T19:07:53Z |
dc.date.available | 2023-02-06T19:07:53Z |
dc.date.issued | 2022 |
dc.identifier.uri | https://repositorio.unal.edu.co/handle/unal/83327 |
dc.description | graficas, tablas |
dc.description.abstract | La industria de las curtiembres es una de las actividades antropogénicas que más agua consume y, por ende, una de las principales generadoras de aguas residuales. Entre los procesos involucrados en la obtención del cuero, la etapa de teñido contribuye con el ca. 6% de las aguas residuales producidas, aporta color, nitrógeno amoniacal, y en general aumenta la carga contaminante del efluente. El municipio de Belén (Nariño) posee una participación considerable del número de curtiembres del país (ca. 9% con 46 curtiembres activas). Esto define una serie de importantes desafíos ambientales (relacionados con la necesidad de tratar grandes volúmenes de aguas residuales contaminadas) y económicos (pues de esta industria depende el 95% de la población de Belén). En esta tesis de maestría en ingeniería – ingeniería química se evaluó la capacidad del proceso oxidativo Fenton en la degradación del colorante y materia orgánica contenidos en el agua residual generada en la etapa de teñido del cuero de una curtiembre representativa del municipio de Belén. Se realizó una caracterización de los parámetros fisicoquímicos del efluente en función de la normativa ambiental nacional vigente. En esta tesis, las condiciones óptimas de operación del proceso Fenton Batch, se definieron mediante: (i) un estudio preliminar que permitió acotar los intervalos de operación de los factores más significativos en el proceso (pH, [H2O2] y [Fe2+]); (ii) un diseño experimental del tipo Box-Behnken y análisis de estadístico de los resultados obtenidos; (iii) metodología de superficie de respuesta y herramientas numéricas para la optimización multiobjetivo. Las siguientes condiciones de operación: pH inicial = 3.15, [H2O2] = 5.38 mM, [Fe2+] = 0.981 mM y 10 minutos de tratamiento (definidos de un estudio cinético) permitieron maximizar la decoloración del efluente (> 97%) y minimizar los costos operacionales (0.0112 USD/m3). Así, se obtuvo un efluente que cumplió con la normatividad ambiental nacional vigente. Adicionalmente, sus características de biodegradabilidad y toxicidad mejoraron notablemente. (Texto tomado de la fuente) |
dc.description.abstract | Tannery industry is one of the anthropogenic activities that most water consumes and, therefore, one of the main wastewater generators. Within the steps involved in leather’s processing, the dyeing stage contributes with ca. 6% of the wastewater produced, provides color, ammoniacal nitrogen and, in general, increases the contaminant load of the effluent. The municipality of Belén (Nariño) has a considerable participation in the number of tanneries in the country (approx. 9% with 46 active tanneries). This defines a series of important environmental challenges (related to the need to treat large volumes of contaminated wastewater) and economic trials (because 95% of Belén population depends on this industry). In this M. Sc. thesis in engineering - chemical engineering, the Fenton oxidative process was evaluated for the degradation of the colorant and organic matter contained in the residual water generated in the leather dyeing stage of a representative tannery from the municipality of Belén. The characterization of the physicochemical parameters of the effluent was carried out based on current national environmental regulations. The optimal operating conditions for the Fenton process were determined through: (i) a preliminary experimental study that allowed narrowing down the operating ranges of the most significant factors in the process (pH, [H2O2], and [Fe2+]); (ii) an experimental design of the Box-Behnken type and statistical analysis of the results obtained; (iii) response surface methodology and numerical tools for multi-objective optimization. The following operating conditions: initial pH = 3.15, [H2O2] = 5.38 mM, [Fe2+] = 0.981 mM and 10 minutes of treatment (defined from a kinetic study) allowed maximizing the discoloration of the effluent (> 97%) and minimizing the operational costs (0.0112 USD/m3). The treated effluent complied with current national environmental regulations. In addition, its biodegradability and toxicity characteristics were remarkably improved. |
dc.format.extent | xviii, 115 páginas |
dc.format.mimetype | application/pdf |
dc.language.iso | spa |
dc.publisher | Universidad Nacional de Colombia |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ |
dc.subject.ddc | 660 - Ingeniería química::661 - Tecnología de químicos industriales |
dc.title | Evaluación de métodos de tratamiento para la degradación de colorante en el agua residual de la industria de las curtiembres |
dc.type | Trabajo de grado - Maestría |
dc.type.driver | info:eu-repo/semantics/masterThesis |
dc.type.version | info:eu-repo/semantics/acceptedVersion |
dc.publisher.program | Manizales - Ingeniería y Arquitectura - Maestría en Ingeniería - Ingeniería Química |
dc.contributor.researchgroup | Grupo de Investigación en Procesos Reactivos Intensificados con Separación y Materiales Avanzados (Prisma) |
dc.description.degreelevel | Maestría |
dc.description.degreename | Magíster en Ingeniería - Ingeniería Química |
dc.description.researcharea | Procesos Avanzados de Oxidación |
dc.identifier.instname | Universidad Nacional de Colombia |
dc.identifier.reponame | Repositorio Institucional Universidad Nacional de Colombia |
dc.identifier.repourl | https://repositorio.unal.edu.co/ |
dc.publisher.faculty | Facultad de Ingeniería |
dc.publisher.place | Manizales, Colombia |
dc.publisher.branch | Universidad Nacional de Colombia - Sede Manizales |
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dc.rights.accessrights | info:eu-repo/semantics/openAccess |
dc.subject.proposal | Fenton |
dc.subject.proposal | Degradación de colorante |
dc.subject.proposal | Proceso avanzado de oxidación |
dc.subject.proposal | Agua residual curtiembres |
dc.subject.proposal | Etapa de teñido |
dc.subject.proposal | Dye degradation |
dc.subject.proposal | Advanced oxidation processes |
dc.subject.proposal | Tannery wastewater |
dc.subject.proposal | Dyeing stage |
dc.subject.unesco | Contaminación industrial |
dc.subject.unesco | Pollution industrielle |
dc.title.translated | Evaluation of treatment methods for dye degradation in wastewater from tannery industry |
dc.type.coar | http://purl.org/coar/resource_type/c_bdcc |
dc.type.coarversion | http://purl.org/coar/version/c_ab4af688f83e57aa |
dc.type.content | Image |
dc.type.content | Text |
oaire.accessrights | http://purl.org/coar/access_right/c_abf2 |
dcterms.audience.professionaldevelopment | Bibliotecarios |
dcterms.audience.professionaldevelopment | Estudiantes |
dcterms.audience.professionaldevelopment | Investigadores |
dcterms.audience.professionaldevelopment | Maestros |
dcterms.audience.professionaldevelopment | Padres y familias |
dcterms.audience.professionaldevelopment | Público general |
dc.description.curriculararea | Química Y Procesos |
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