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Selección de un agente dispersante compatible con recubrimientos base agua y base solvente para su uso en concentrados pigmentarios universales

dc.rights.licenseAtribución-NoComercial 4.0 Internacional
dc.contributor.advisorBoyacá Mendivelso, Luis Alejandro
dc.contributor.authorFernández Ramírez, Juan Sebastián
dc.date.accessioned2023-11-29T03:28:33Z
dc.date.available2023-11-29T03:28:33Z
dc.date.issued2023
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/85015
dc.descriptionilustraciones, tablas
dc.description.abstractEste trabajo se enfoca en ofrecer recursos técnicos para la correcta selección de un agente dispersante dirigido a formular concentrados pigmentarios universales que sean compatibles en sistemas de recubrimientos base agua y base solvente – alquídicos. El desarrollo de este trabajo contempla una clasificación de los agentes dispersantes disponibles en el mercado colombiano, y una caracterización por espectroscopía infrarroja para hacer una primera selección de los agentes dispersantes que ofrecen características de universalidad. En este primer paso se selecciona un dispersante oligomérico de poliéster modificado y un dispersante acrílico de bloques AB. Una vez caracterizados los grupos funcionales se realiza un diseño de experimentos factorial 32 para la determinación de la relación óptima de concentración de pigmento y dispersante. Finalmente, con los concentrados pigmentarios formulados con la relación óptima, se realizan ensayos de estabilidad y compatibilidad para evaluar el desempeño ofrecido por el dispersante. Los datos experimentales obtenidos presentan que el dispersante oligomérico posee una mayor compatibilidad en medios acuosos y solventes que el dispersante acrílico por bloques
dc.description.abstractThis work focuses on providing technical resources for the proper selection of a dispersing agent aimed at universal pigment concentrates that are compatible in water-based and solvent-based coatings. The development of this work includes a classification of dispersing agents available in the Colombian market, and a characterization by infrared spectroscopy to make a first selection of dispersing agents that offer universal characteristics. In this first step, a modified polyester oligomeric dispersant and an AB block acrylic dispersant are selected. Once the functional groups are characterized, a 32 factorial design of experiments is carried out to determine the optimal pigment concentration and dispersant ratio. Finally, with the pigment concentrates formulated with the optimal ratio, stability and compatibility tests are carried out to determine the performance offered by the dispersing agent. The experimental data obtained shows that the oligomeric dispersant has greater compatibility in aqueous and solvent media than the acrylic dispersant.
dc.format.extentxvii, 99 páginas
dc.format.mimetypeapplication/pdf
dc.language.isospa
dc.publisherUniversidad Nacional de Colombia
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.subject.ddc540 - Química y ciencias afines
dc.titleSelección de un agente dispersante compatible con recubrimientos base agua y base solvente para su uso en concentrados pigmentarios universales
dc.typeTrabajo de grado - Maestría
dc.type.driverinfo:eu-repo/semantics/masterThesis
dc.type.versioninfo:eu-repo/semantics/acceptedVersion
dc.publisher.programBogotá - Ingeniería - Maestría en Ingeniería - Ingeniería Química
dc.description.degreelevelMaestría
dc.description.degreenameMagíster en Ingeniería - Ingeniería Química
dc.identifier.instnameUniversidad Nacional de Colombia
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombia
dc.identifier.repourlhttps://repositorio.unal.edu.co/
dc.publisher.facultyFacultad de Ingeniería
dc.publisher.placeBogotá, Colombia
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotá
dc.relation.referencesAgbo, C., Jakpa, W., Sarkodie, B., Boakye, B. & Fu, S. (2017). A Review on the Mechanism of Pigment Dispersión. Journal of Dispersion Science and Technology, (39:6), 874 – 889. https://doi.org/10.1080/01932691.2017.1406367
dc.relation.referencesAFCONA (2005). Dispersing Technology. AFCONA. Recuperdado el 20 de febrero de 2023. https://www.afcona.com.my/static.php?sTpl=dispersing
dc.relation.referencesAlexandrova, L., Grigorov, L., Khristov, K. & Petkova, H. (2016) Effects of pH on Wetting Behavior of ‘Star-Like’ Block Copolymer Surfactant Solutions. Colloids Surface A: Physicochemical and Engineering Aspects, volumen (519), 78 - 86. https://doi.org/10.1016/j.colsurfa.2016.03.070
dc.relation.referencesAuschra, C., Eckstein, Er., Mühlebach, A., Zink, M. & Rime, F. (2002). Design of New Pigment Dispersants by Controlled Radical Polymerization. Progress in Organic Coatings. 45 (2 – 3). 83 – 93. https://doi.org/10.1016/S0300-9440(02)00048-6
dc.relation.referencesAtsushi, T., Kunio Y., Masayuki Y., Satoru K. & Kazuhiro S. (1994). Shear viscosity behavior of flocculated suspensions. Powder Technology. 78 (2). 165-172. https://doi.org/10.1016/0032-5910(93)02800-P
dc.relation.referencesBASF Formulation Additivies. (s.f). Little helpers Love Great Achivements Practical Guide to Dispering Agents. BASF. https://dispersions resins.basf.com/global/en/performance_and_formulation_additives/products/disper sing-agents-landing-page.html
dc.relation.referencesBieleman, J. (2000). Additives for Coatings. Wiley-VCH
dc.relation.referencesBuxbaum, G. & Pfaff, G. (2005). Industrial Inorganic Pigments. Wiley-VCH GmbH & Co KGaA
dc.relation.referencesBYK. (s.f.). Wetting and dispersing agents. BYK. Recuperado el 20 de febrero de 2023. https://ebooks.byk.com/en/wetting-and-dispersing/why-do-we-use-wetting-and dispersing-additives
dc.relation.referencesEchavarría, N. & Gamez, A. (20 de febrero de 2023). Estudio de Mercado de las Pinturas en Colombia. Centro de Producción más Limpia y Tecnologías Ambientales. https://cambioclimatico-regatta.org/index.php/es/instituciones-clave/item/centro nacional-de-produccion-mas-limpia-y-tecnologias-ambienta
dc.relation.referencesEttelaie, R., Holmes, M., Chen, J. & Farshchi, A. (2016). Steric Stabilising Properties of Hydrophobically Modified Starch: Amylose vs. Amylopectin. Food Hydrocolloids, 58. 364–377. https://doi.org/10.1016/j.foodhyd.2016.03.004
dc.relation.referencesGunawant, P. & Jagtap, R. (2016). Desig nans Synthesis of Polymeric Dispersant for Water-borne Paint by Atom Transfer Radical Polymerization. Designed Monomers and Polymers. 19 (3). 256 – 270. http://dx.doi.org/10.1080/15685551.2015.1136534
dc.relation.referencesHagiwara, S. Tsutsumi, K. & Takahashi, H. (1977). Surface Polarity of Carbon Blacks. Carbon. 16 (2). 89 – 93. https://doi.org/10.1016/0008-6223(78)90003-9
dc.relation.referencesHakeim, O. A., Diab, H. A & Adams, J. (2015). Preparation and Characterization of UV Curable Encapsulated Phthalocyanine Blue Pigment. Progress in Organic Coatings, 84. 70– 78. https://doi.org/10.1016/j.porgcoat.2015.02.007
dc.relation.referencesHeilen, W. (2009). Additives for Waterborne Coatings. Vincentz Network
dc.relation.referencesHerbst, W. & Hunger, K. (2004). Industrial Organic Pigments. Wiley-VCH GmbH & Co KGaA
dc.relation.referencesJärnström, J., Väisänen, M., Lehto, R., Jäsberg, A., Timonen, J. & Peltonen, J. (2010). Effect of Latex on Surface Structure and Wetting of Pigment Coatings. Colloids Surface A: Physicochemical and Engineering Aspects, 353 (2). 104–116. https://doi.org/10.1016/j.colsurfa.2009.11.001
dc.relation.referencesLin, L. (2003). Mechanisms of Pigment Dispersion. Pigment Resin Technologies, 32 (2). 78– 88, https://doi.org/10.1108/03699420310464784
dc.relation.referencesMelo, O., López, L. & Melo, S. (2020). Diseño de Experimentos Métodos y Aplicaciones. Universidad Nacional de Colombia
dc.relation.referencesMontgomery, D.C. (2017). Design and Analysis of Experiments. Jhon Wiley & Sons.
dc.relation.referencesMüller, B. (2010). Understanding Additives. Vincentz Network
dc.relation.referencesMilanovic, N. & Casey, B. O. (2017). An efficient approach to dispersing pigments. Evonik Industries AG.
dc.relation.referencesMcKeen, L. (2013). Fluorinated Coatings: Technoloy, History, and Applications. En Sina Ebnesajjad (Ed.), Introduction to Fluoropolymers. (pp 45 – 58). William Andrew publishing. https://doi.org/10.1016/B978-1-4557-7442-5.00011-5
dc.relation.referencesOrion (s.f.). What is a carbon black? Orion. Recuperado el 15 de marzo de 2023. https://orioncarbons.com/what_is_carbon_black
dc.relation.referencesOrom Colorants. (s.f.). Pigment Concentrates. Orom Colorants. Recuperado el 20 de febrero de 2023. http://www.orom.co.il/pigment-concentrates
dc.relation.referencesPaajanen, H. (2018). Pigment Dispersion Processing, Optimization for Higher Pigmentation [Master thesis, Land University]. Repositorio institucional https://lup.lub.lu.se/student-papers/search/publication/8947886
dc.relation.referencesPirrung, F., Quednau, P. & Auschra, C. (2002). Wetting and Dispersing Agents. Chimia, 56 (5), 170 – 176
dc.relation.referencesRai, S. & Lokhandwala, S. (2015). Important Aspects Involved in Pilot Scale Production of Modern Paints and Coatings A2. En Tiwari, Atul (Ed.), Intelligent Coatings for Corrosion Control. (pp. 335–361). Hihara, L. H. https://doi.org/10.1016/B978-0-12- 411467-8.00009-X
dc.relation.referencesSaindane, P. & Jagtap, R. N. (2015). Copolymerization of Amphiphilic Poly (ethyl acrylate bacrylic acid) as Wetting and Dispersing Agents for Water Borne Coating. Progress in Organic Coatings, 79. 106–114. https://doi.org/10.1016/j.porgcoat.2014.07.016
dc.relation.referencesSun, Y., Wang, Y. & Zhitomirsky, I. (2013). Dispersing Agents for Electrophoretic Deposition of TiO2 and TiO2–Carbon Nanotube Composites. Surfactant Solutions. Colloids Surface A: Physicochemical and Engineering Aspects. 418. 131–138. https://doi.org/10.1016/j.colsurfa.2012.11.030
dc.relation.referencesSun, X., Liu, Y., Li, Y., Wu, M. & Zhu, D. (2016). Simultaneous Measurement of Brown Core and Soluble Solids Content in Pear by On-Line Visible and Near Infrared Spectroscopy. Postharvest Biology and Technology, 116. 80–87. https://doi.org/10.1016/j.postharvbio.2016.01.009
dc.relation.referencesSusana, L, Campaci, F. & Santomaso, A. (2021). Wettability of mineral and metalic powders: Applicability and limitations of Sessile Drop Method and Washburn´s technique. Powder Technology, volumen 226. 68 – 77. https://doi.org/10.1016/j.powtec.2012.04.016
dc.relation.referencesSis, H. & Birinci, M. (2014). Wetting and Rheological Characteristics of Hydrophobic Organic Pigments in Water in the Presence of Non-Ionic Surfactants. Colloids Surface A: Physicochemical and Engineering Aspects, 455. 58–66. https://doi.org/10.1016/j.colsurfa.2014.04.042
dc.relation.referencesSchmitz, J., Frommelius, H., Pegelow, U., Schulte, H. G. & Höfer, R. (1999). A New Concept for Dispersing Agents in Aqueous Coatings. Prog. Org. Coat, volumen (35-1), 191– 196. https://doi.org/10.1016/S0300-9440(99)00028-4
dc.relation.referencesStojanovic, M., Aleksic, J. & Baranac-Stojanovic. (2015). The effecto of steric repulsion on the torsional potential of n-butane: a theoretical study. 71 (32). 5119 – 5123. https://doi.org/10.1016/j.tet.2015.06.002
dc.relation.referencesUK Seung. (s.f.). Products Panax Color. UK Seung. Recuperado el 15 de marzo de 2023. http://www.ukseung.co.kr/esub/product_pro_01_03.aspx
dc.relation.referencesWu, S., Kenneth, J & Brzozowski. (1971). Surface Free Energy and Polarity of Organic Pigments. Journal of Colloid and Interface Science. 37 (4). 686 – 690. https://doi.org/10.1016/0021-9797(71)90347-X
dc.rights.accessrightsinfo:eu-repo/semantics/openAccess
dc.subject.proposalConcentrado pigmentario universal
dc.subject.proposalAgente dispersante
dc.subject.proposalProcesos de dispersión
dc.subject.proposalEstabilización de la dispersión
dc.subject.proposalDiseño de experimentos
dc.subject.proposalConcentrate universal pigment
dc.subject.proposalDispersing agent
dc.subject.proposalDispersion process
dc.subject.proposalDispersion stabilization
dc.subject.proposalExperimental design
dc.title.translatedSelection of a dispersing agent compatible in water-based and solvent-based coatings for use in universal pigment concentrates
dc.type.coarhttp://purl.org/coar/resource_type/c_bdcc
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.contentText
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2
dcterms.audience.professionaldevelopmentEstudiantes
dcterms.audience.professionaldevelopmentInvestigadores
dcterms.audience.professionaldevelopmentMaestros
dcterms.audience.professionaldevelopmentPúblico general
dc.description.curricularareaQuímica.Sede Bogotá
dc.contributor.orcidFernández Ramírez, Juan Sebastián [0000000297801642]
dc.contributor.cvlacFernández Ramírez Juan Sebastián


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Atribución-NoComercial 4.0 InternacionalEsta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial 4.0.Este documento ha sido depositado por parte de el(los) autor(es) bajo la siguiente constancia de depósito