Producción de acetato de fusel por destilación reactiva
| dc.contributor.advisor | Rodríguez Niño, Gerardo | spa |
| dc.contributor.advisor | Gil Chaves, Iván Darío | spa |
| dc.contributor.author | Sánchez Correa, César Augusto | spa |
| dc.contributor.researchgroup | Grupo de Investigación en Procesos Químicos y Bioquímicos | spa |
| dc.date.accessioned | 2020-07-06T15:55:04Z | spa |
| dc.date.available | 2020-07-06T15:55:04Z | spa |
| dc.date.issued | 2020-07-02 | spa |
| dc.description.abstract | En este trabajo se investigan las trayectorias directas de procesos de destilación reactiva (DR) para la síntesis de acetatos a partir de la esterificación de ácido acético con aceite de fusel (AF). El problema se encuentra limitado a una descripción aproximada donde el AF se considera como una mezcla de alcohol isoamílico + agua + etanol. Esta versión simplificada del problema puede ocurrir aproximadamente en la práctica. En este contexto el objetivo principal del trabajo consistió en diseñar un proceso de DR para la producción de acetato de fusel. Los objetivos específicos son: a) desarrollar un modelo termodinámico adecuado para predecir los equilibrios de fases líquido – vapor y líquido – líquido – vapor del sistema multicomponente a partir de la información experimental (generada y recopilada en la literatura) de los subsistemas binarios y ternarios; b) desarrollar un modelo cinético apropiado para describir la esterificación directa del ácido acético con aceite de fusel en fase líquida; c) sintetizar a nivel conceptual alternativas de proceso para la tecnología de DR; y d) calcular los tamaños de los equipos y el costo total anualizado para alternativas de proceso técnicamente factibles. Desde el punto de vista experimental, se generó información nueva en dos casos: a) para el equilibrio líquido – vapor de las mezclas binarias de acetatos; y b) datos de velocidad de reacción para la esterificación de ácido acético con alcohol isoamílico (y con mezclas de alcohol isoamílico y etanol) utilizando la resina Amberlyst 70 como catalizador. La información experimental se utilizó para correlacionar y validar los modelos termodinámico y cinético. Desde el punto de vista teórico se desarrolló la caracterización termodinámica completa del sistema multicomponente reactivo, y se usaron los planos de fases reactivos para sintetizar estructuras de proceso que se caracterizaron utilizando los estados estacionarios de máxima conversión. Se encontró que es posible implementar un proceso de DR con alimentos en la proporción estequiométrica, altas conversiones (~99%) y alta recuperación de los acetatos (≥99%). | spa |
| dc.description.abstract | This work is a research on the direct trajectories of a reactive distillation process to synthetize acetates by the acetic acid esterification with fusel oil. The problem is bounding into the approximated description where the fusel oil is modeled as a mixture of isoamyl alcohol + ethanol + water. This simplified version of the problem can occur in the real world. In this context, the main objective of this work was to design a reactive distillation process for the fusel acetate production. The specific objectives are: a) to develop a thermodynamic model suitable for the prediction of the multicomponent phase equilibria (vapor – liquid and vapor – liquid – liquid) from experimental information (generated and extracted from literature) related with the associated binary and ternary subsystems; b) to develop a kinetic model suitable to describe the acetic acid esterification with fusel oil in the liquid phase; c) to synthetize, in the conceptual level, process alternatives for the reactive distillation technology; and d) to calculate the dimensions for the process units and the total annualized cost for the technically feasible process alternatives. From the experimental view, new information was generated in two subjects: a) vapor – liquid equilibrium for binary mixtures of acetates; and b) kinetic data for the liquid phase acetic acid esterification with isoamyl alcohol (or with binary mixtures of isoamyl alcohol and ethanol) using the Amberlyst 70 resin as catalyst. The experimental information was used to correlate and validate the thermodynamic and kinetic models. From a theoretical view, a complete thermodynamic characterization for the multicomponent reactive system was calculated, and the reactive phase diagrams were used to synthesize process structures that were characterized using the stationary states with maximum conversion. It was found that is possible to implement a reactive distillation process with the feeds in the stoichiometric proportion, high conversions for the reactants (~ 99 %) and high recoveries for the acetates (≥ 99 %) | spa |
| dc.description.degreelevel | Doctorado | spa |
| dc.format.extent | 167 | spa |
| dc.format.mimetype | application/pdf | spa |
| dc.identifier.uri | https://repositorio.unal.edu.co/handle/unal/77741 | |
| dc.language.iso | spa | spa |
| dc.publisher.branch | Universidad Nacional de Colombia - Sede Bogotá | spa |
| dc.publisher.program | Bogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería Química | spa |
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| dc.rights | Derechos reservados - Universidad Nacional de Colombia | spa |
| dc.rights.accessrights | info:eu-repo/semantics/openAccess | spa |
| dc.rights.license | Atribución-SinDerivadas 4.0 Internacional | spa |
| dc.rights.spa | Acceso abierto | spa |
| dc.rights.uri | http://creativecommons.org/licenses/by-nd/4.0/ | spa |
| dc.subject.ddc | 660 - Ingeniería química::664 - Tecnología de alimentos | spa |
| dc.subject.ddc | 660 - Ingeniería química | spa |
| dc.subject.proposal | aceite de fusel | spa |
| dc.subject.proposal | isoamyl acetate | eng |
| dc.subject.proposal | ethyl acetate | eng |
| dc.subject.proposal | destilación reactiva | spa |
| dc.title | Producción de acetato de fusel por destilación reactiva | spa |
| dc.title.alternative | Fusel acetate production by reactive distillation | spa |
| dc.type | Libro | spa |
| dc.type.coar | http://purl.org/coar/resource_type/c_2f33 | spa |
| dc.type.coarversion | http://purl.org/coar/version/c_970fb48d4fbd8a85 | spa |
| dc.type.content | Text | spa |
| dc.type.driver | info:eu-repo/semantics/book | spa |
| dc.type.redcol | http://purl.org/redcol/resource_type/LIB | spa |
| dc.type.version | info:eu-repo/semantics/publishedVersion | spa |
| oaire.accessrights | http://purl.org/coar/access_right/c_abf2 | spa |