Desarrollo de sistemas fotocatalíticos tipo Ba1-xMxTiO3 (M = Fe, Al) soportados en biocarbonos activados para la remoción de contaminantes emergentes presentes en matrices acuosas

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dc.contributor.advisorMoreno Aldana, Luis Carlosspa
dc.contributor.advisorAgamez-Pertuz, Yazmin Yanethspa
dc.contributor.authorVarela Olivera, Christian Fabianspa
dc.contributor.cvlacVarela Olivera, Christian Fabian [0001586304]spa
dc.contributor.googlescholarVarela Olivera, Christian Fabian [Christian F. Varela]spa
dc.contributor.orcidVarela Olivera, Christian Fabian [0000-0002-1691-542X]spa
dc.contributor.researchgrouplaboratorio de Investigación en Combustibles y Energíaspa
dc.contributor.scopusVarela Olivera, Christian Fabian [57222088629]spa
dc.date.accessioned2025-07-03T21:48:59Z
dc.date.available2025-07-03T21:48:59Z
dc.date.issued2025
dc.descriptionilustraciones, diagramasspa
dc.description.abstractLa presencia de contaminantes emergentes en el agua representa graves riesgos para el medio ambiente y la salud humana, por lo que es necesario investigar nuevas y menores metodologías que permitan la eliminación eficiente de estos contaminantes. En este contexto, la presente tesis doctoral se enfocó en el desarrollo de nuevos materiales para la remoción mediante adsorción/fotocatálisis de contaminantes emergentes en matriz acuosa. Los estudios se realizaron en tres etapas, en la primera se prepararon biocarbonos activados, y se evaluó su desempeño en la remoción adsorptiva de acetaminofén y amoxicilina, con el fin de seleccionar el material adecuado a ser empleado como soporte carbonoso. En la segunda etapa, se sintetizaron materiales tipo BaTiO3 sustituidos con hierro y aluminio, y se determinó el efecto de la sustitución en la actividad fotocatalítica de los materiales obtenidos. En la tercera etapa se prepararon varios materiales compuestos a partir de un biocarbón de tusa de maíz activado en ZnCl2 y el semiconductor con Ba0.90Fe0.10TiO3, los cuales habían demostrado individualmente la mayor capacidad de remoción. Se demostró que el soporte carbonoso, los semiconductores, y subsecuentemente, los materiales compuestos preparados presentan una alta efectividad en la remoción de fármacos y microplástico presentes en matrices acuosas. De esta manera, la presente investigación presenta un aporte significativo en el desarrollo de alternativas metodológicas para lograr una remoción eficiente y asequible de contaminantes emergentes mediante adsorción/fotocatálisis. (Texto tomado de la fuente).spa
dc.description.abstractThe presence of emerging pollutants in water poses serious risks to the environment and human health, making it necessary to investigate new and less costly methodologies that efficiently remove these contaminants. In this sense, the present doctoral thesis focused on developing new materials for the removal of emerging pollutants in aqueous matrices through adsorption/photocatalysis. The studies were conducted in three stages. In the first stage, activated biochars were prepared, and their performance in the adsorptive removal of acetaminophen and amoxicillin was evaluated, aiming to select the appropriate material to be used as a carbonaceous support. In the second stage, BaTiO3-type materials substituted with iron and aluminum were synthesized, and the effect of substitution on the photocatalytic activity of the obtained materials was determined. In the third stage, several composites were prepared using corn corn-bob biochar activated with ZnCl2 and the semiconductor Ba0.90Fe0.10TiO3, which had individually demonstrated the highest removal capacity. It was proven that the carbonaceous support, semiconductors, and subsequently, the prepared composites exhibit high effectiveness in removing drugs and microplastics in aqueous matrices. This research represents a significant contribution to developing methodological alternatives for achieving efficient and affordable removal of emerging contaminants through adsorption/photocatalysis.eng
dc.description.degreelevelDoctoradospa
dc.description.degreenameDoctor en Ciencias - Químicaspa
dc.description.researchareaNuevos materiales y procesosspa
dc.format.extentxxiv, 264 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/88288
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.departmentDepartamento de Químicaspa
dc.publisher.facultyFacultad de Cienciasspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ciencias - Doctorado en Ciencias - Químicaspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseReconocimiento 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/spa
dc.subject.ddc540 - Química y ciencias afines::543 - Química analíticaspa
dc.subject.ddc540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesspa
dc.subject.proposalBiocarbónspa
dc.subject.proposalBaTiO3spa
dc.subject.proposalAdsorciónspa
dc.subject.proposalFotocatálisisspa
dc.subject.proposalAcetaminofénspa
dc.subject.proposalAmoxicilinaspa
dc.subject.proposalMicroplásticospa
dc.subject.proposalBiochareng
dc.subject.proposalBaTiO3eng
dc.subject.proposalAdsorptioneng
dc.subject.proposalPhotocatalysiseng
dc.subject.proposalAcetaminopheneng
dc.subject.proposalAmoxicillineng
dc.subject.proposalMicroplasticeng
dc.subject.unescoInvestigación químicaspa
dc.subject.unescoChemical researcheng
dc.subject.wikidatafotocatálisisspa
dc.subject.wikidataphotocatalysiseng
dc.subject.wikidatacontaminantespa
dc.subject.wikidatacontaminanteng
dc.titleDesarrollo de sistemas fotocatalíticos tipo Ba1-xMxTiO3 (M = Fe, Al) soportados en biocarbonos activados para la remoción de contaminantes emergentes presentes en matrices acuosasspa
dc.title.translatedDevelopment of photocatalytic systems of type Ba1-XMXTiO3 (M = Fe, Al) supported on activated biochars for the removal of emerging pollutants in aqueous matriceseng
dc.typeTrabajo de grado - Doctoradospa
dc.type.coarhttp://purl.org/coar/resource_type/c_db06spa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
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dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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