Resistencia al desgaste de recubrimientos de (Ti,Cr,Al)N-Cu producidos por medio de la técnica de co-sputtering magnetrón reactivo

dc.contributor.advisorCapote Rodríguez, Gilspa
dc.contributor.advisorOlaya Flórez, Jhon Jairospa
dc.contributor.authorVallejo Bastidas, Fabio Fernandospa
dc.contributor.orcidVallejo Bastidas, Fabio Fernando [0000000164272054]spa
dc.contributor.researchgroupGrupo de Investigación Afis (Análisis de Fallas, Integridad y Superficies)spa
dc.date.accessioned2025-04-29T13:54:51Z
dc.date.available2025-04-29T13:54:51Z
dc.date.issued2023
dc.descriptionilustraciones, diagramas, fotografías a color, tablasspa
dc.description.abstractEn este trabajo de investigación se sintetizaron recubrimientos de (Al,Ti,Cr)N con diferentes contenidos de cobre mediante la técnica de co-sputtering magnetrón reactivo y la técnica de impulso de alta potencia (HiPIMS) depositado sobre sustratos de acero AISI 4340 y WC-Co. Se evaluó el efecto de los recubrimientos en las propiedades mecánicas y tribológicas al variar los contenidos de cobre entre 0 y 1,74 at. % Cu, para co-sputtering, y entre 0 y 4,48 at. % para HiPIMS. Además, se estudió la composición química, estructural y morfológica sobre las propiedades del recubrimiento. La composición química reveló un recubrimiento cuasi estequiométrico. Los diagramas de XRD mostraron una estructura tipo B1, FCC-NaCl con un crecimiento preferencial en la orientación (111) para ambas técnicas. La morfología de los recubrimientos depositados por sputtering reveló una estructura columnar, piramidal y porosa. Los recubrimientos de HIPIMS mostraron una transición de una morfología lenticular a una piramidal con la adición de Cu. Los recubrimientos de HIPIMS con 4,34 at. %Cu resultaron en una capa más densa y homogénea, sin vacíos o poros, en comparación con los recubrimientos de sputtering. La dureza incrementó con el aumento del Cu en ambas técnicas. Además, se evidenció un incremento del doble para HiPIMS pasando de un promedio de 11,5 GPa ± 0,3 a 23,4 GPa ± 1,75. En MS, el coeficiente de fricción, CoF en aire, disminuyó ligeramente con el aumento de at. % Cu, mientras que el CoF en aceite aumentó ligeramente. En HiPIMS, el CoF en aire disminuyó con el incremento del at. % Cu, mientras que el CoF en aceite disminuyó inicialmente y luego se estabilizó. Se observó que HiPIMS reduce el CoF en aire entre un 46% a 47% y, en aceite, entre un 16% a 23% respecto a MS. En cuanto a la tasa de desgaste, se observó que, en aire, aumentó con el incremento del at % Cu, mientras que en aceite, disminuyó inicialmente y luego aumentó, alcanzando un máximo en 1,09 at % Cu para 4340. En HiPIMS, la tasa de desgaste disminuyó con el incremento del Cu tanto para aceite como para aire sobre los WC-Co. En general, se observó que la tasa de desgaste en aire disminuye un 22,77 a 29,35% sobre WC-Co y 4340, respectivamente respecto a MS y, en aceite, casi un 100% para el 4340 y un 84% para WC-Co. La resistencia a la polarización de los recubrimientos depositados por HIPIMS aumentó en un 49,73% respecto a los depositados por MS sobre 4340 y en una unidad sobre WC-Co. Los recubrimientos depositados mediante HiPIMS mostraron un mejor desempeño debido a la alta energía de los iones que se depositan en la superficie del sustrato (Texto tomado de la fuente).spa
dc.description.abstractThis research work involved synthesizing (Al,Ti,Cr)N coatings with different copper contents using the reactive magnetron co-sputtering technique and the high-power impulse magnetron sputtering technique (HiPIMS) deposited on AISI 4340 steel and WC-Co substrates. The study aimed to assess the impact of copper content on the mechanical and tribological properties of the coatings. Copper contents were adjusted between 0 and 1,74 at. % Cu, for coatings deposited by co-sputtering and between 0 and 4,48 at. % for HiPIMS deposited coatings. In addition, the chemical composition, microstructural and morphological properties of the coatings were studied. The chemical composition revealed the formation of a quasi-stoichiometric coating. XRD diagrams showed a B1, FCC-NaCl type structure with preferential growth in orientation (111). The morphology analysis of the sputtering-deposited coatings revealed a columnar, pyramidal, and porous structure. Notably, HIPIMS coatings exhibited a transition from lenticular to pyramidal morphology with the addition of Cu. Coatings produced through HIPIMS with 4,34 at. %Cu resulted in a denser and more homogeneous layer, with no voids or pores, in contrast to sputtering coatings. Hardness increased with the growing Cu content in both techniques. Specifically, in HiPIMS there was a twofold increase from an average of 11,5 GPa ± 0,3 to 23,4 GPa ± 1.75. Regarding the coefficient of friction, in air, CoF slightly decreasedwith increasing at. % Cu in MS, while in oil, it exhibited a slight increase. In HiPIMS, the CoF in air decreased with increasing at. % Cu, while in oil, it initially decreased and then stabilized. Compared to MS, HiPIMS resulted in a notable reduction in CoF, decreasing by 46% to 47% in air and by 16% to 23% in oil. Examining the wear rate, it was observed that in air, it increased with the rise in at % Cu, while in oil, it initially decreased and then increased, reaching a maximum of 1,09 at % Cu for 4340. In HiPIMS, the wear rate decreased with the increase of Cu for both oil and air on the WC-Co. Overall, the wear rate in air decreased by 22,77 to 29,35% for WC-Co and 4340, respectively, inMS. In oil, the decrease was almost 100% for 4340 and 84% for WC-Co. Furthermore, the polarization resistance of coatings deposited by HIPIMS increased by 49,73% compared to those deposited by MS on 4340 and in one unit on WC-Co. Coatings deposited by HiPIMS showed better performance due to the high energy of the ions deposited on the substrate surface.eng
dc.description.degreelevelDoctoradospa
dc.description.degreenameDoctor en Ingeniería Mecánica y Mecatrónicaspa
dc.description.researchareaIngeniería de Fabricación y Materialesspa
dc.format.extent219 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/88135
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Ingenieríaspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ingeniería - Doctorado en Ingeniería - Ingeniería Mecánica y Mecatrónicaspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.subject.ddc620 - Ingeniería y operaciones afines::629 - Otras ramas de la ingenieríaspa
dc.subject.lembREVESTIMIENTOS METALICOSspa
dc.subject.lembMetal coatingeng
dc.subject.lembREVESTIMIENTOS PROTECTORESspa
dc.subject.lembProtective coatingseng
dc.subject.lembPULVERIZACION CATODICA (METALIZACION)spa
dc.subject.lembCathode sputtering (plating process)eng
dc.subject.lembPELICULAS METALICASspa
dc.subject.lembMetallic filmseng
dc.subject.lembRESISTENCIA DE MATERIALESspa
dc.subject.lembStrength of materialseng
dc.subject.lembFATIGA DE MATERIALESspa
dc.subject.lembMaterials - fatigueeng
dc.subject.lembDESCARGAS ELECTRICAS A TRAVES DE GASESspa
dc.subject.lembElectric discharges through gaseseng
dc.subject.lembIONIZACION DE CAPAS INTERNASspa
dc.subject.lembInner-shell ionizationeng
dc.subject.proposalTiCrAlN-Cuspa
dc.subject.proposalSputteringspa
dc.subject.proposalHiPIMSeng
dc.subject.proposalRecubrimiento nanoestructuradospa
dc.subject.proposalDesgastespa
dc.subject.proposalCoeficiente de fricción|
dc.subject.proposalNanocompositosspa
dc.subject.proposalNanostructure coatingeng
dc.subject.proposalWeareng
dc.subject.proposalCoefficient of frictioneng
dc.subject.proposalNanocompositeseng
dc.titleResistencia al desgaste de recubrimientos de (Ti,Cr,Al)N-Cu producidos por medio de la técnica de co-sputtering magnetrón reactivospa
dc.title.translatedWear resistance of AlCrTiN-Cu coatings deposited by reactive magnetron co-sputteringeng
dc.typeTrabajo de grado - Doctoradospa
dc.type.coarhttp://purl.org/coar/resource_type/c_db06spa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/doctoralThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TDspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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