Study of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process

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dc.contributor.advisorChejne, Farid
dc.contributor.advisorGarcía Pérez, Manuel
dc.contributor.authorManrique Waldo, Raiza Johanna
dc.contributor.cvlacRaiza Manrique Waldospa
dc.contributor.googlescholarhttps://scholar.google.com/citations?user=vWdtrjUAAAAJ&hl=es&oi=aospa
dc.contributor.orcidChejne, Farid [0000-0003-0445-7609]
dc.contributor.orcidManrique Waldo, Raiza Johanna [0000-0002-6702-5419]
dc.contributor.researchgatehttps://www.researchgate.net/profile/Raiza-Manriquespa
dc.contributor.researchgroupTermodinámica Aplicada y Energías Alternativasspa
dc.contributor.scopushttps://www.scopus.com/authid/detail.uri?authorId=57195741838spa
dc.date.accessioned2023-06-02T15:17:24Z
dc.date.available2023-06-02T15:17:24Z
dc.date.issued2023-06-01
dc.descriptionilustraciones, diagramasspa
dc.description.abstractBiomass fast pyrolysis bio-oil is a promising alternative to be used as a source of fuels and chemicals. It hosts a wide variety of compounds and comes from renewable sources. Pyrolysis oil is formed by water, light organics (GC/MS detectable compounds), Oligomeric fractions derived from lignin and holocellulose. This dissertation focusses on the identification of oligomeric molecules in the pyrolytic lignin fraction and its catalytic hydrodeoxygenation. This fraction can potentially be used to produce fuels and chemicals via hydrodeoxygenation. The chemical structure of pyrolytic lignin oligomeric molecules is poorly known. In this study, quantum mechanical simulation was used to propose the structures based on calculations of the electronic structure. The DFT calculations were used to identify the thermodynamically most probable chemical structures of pyrolytic lignin molecules resulting from lignin pyrolysis followed by demethylation. The structure of new molecules of dimer, trimer and tetramer oligomers from pyrolytic lignin were proposed. The pyrolytic lignin fraction was further fractionated by solid-liquid extraction and the resulting subfraction thoroughly characterized using FTIR, UV-fluorescence and HSQC-NMR. Ethyl acetate subfractions was characterized by phenolic compounds with methoxyl substituents while acetone and isopropanol subfractions showed more aliphatic characteristics. Pyrolytic lignin fraction from BTG was hydrotreated with a sulfided NiMo/Al2O3 catalyst. Hydrotreating experiments were carried out with mixtures of pyrolytic lignin and yellow grease to obtain liquid fuels. All blends induced coke formation values between 0.7 and 2.5 wt. %, indicating that pyrolytic lignin has potential to reduce coke formation during the process. The results obtained in this thesis will allow the definition of strategies for the design of biorefineries including pyrolytic lignin to obtain products.eng
dc.description.abstractEl bioaceite de pirólisis rápida de biomasa es una alternativa prometedora para ser utilizada como fuente de combustibles y productos químicos. Alberga una amplia variedad de compuestos y proviene de fuentes renovables. El aceite de pirólisis está formado por agua, compuestos orgánicos ligeros (compuestos detectables por GC/MS), fracciones oligoméricas derivadas de la lignina y holocelulosa. Esta tesis se centra en la identificación de moléculas oligoméricas en la fracción pirolítica de lignina y su hidrodesoxigenación catalítica. Esta fracción se puede utilizar potencialmente para la producción de combustibles y productos químicos a través de la hidrodesoxigenación. La estructura química de las moléculas oligoméricas de lignina pirolítica es poco conocida. En este estudio, se utilizó simulación mecánica cuántica para proponer las estructuras basadas en cálculos de la estructura electrónica. Los cálculos DFT se utilizaron para identificar las estructuras químicas termodinámicamente más probables de las moléculas de lignina pirolítica resultantes de la pirólisis de lignina seguida de desmetilación. Se propuso la estructura de nuevas moléculas de oligómeros dímeros, trímeros y tetrámeros a partir de lignina pirolítica. La fracción de lignina pirolítica se fraccionó adicionalmente mediante extracción sólido-líquido y la subfracción resultante se caracterizó minuciosamente usando FTIR, UV-fluorescencia, HSQC-NMR. Las subfracciones de acetato de etilo se caracterizaron por compuestos fenólicos con sustituyentes metoxilo, mientras que la subfracción de acetona e isopropanol mostró características más alifáticas. Se realizó el hidrotratmiento de la fracción de lignina pirolítica de BTG con un catalizador de NiMo/Al2O3 sulfurado. Se realizaron experimentos de hidrotratamiento con mezclas de lignina pirolítica y grasa amarilla para obtener combustibles líquidos. Todas las mezclas obtuvieron valores de formación de coque entre 0,7 y 2,5 en peso. %, lo que indica que la lignina pirolítica tiene potencial para reducir la formación de coque durante el proceso. Los resultados obtenidos en esta tesis permitirán definir estrategias para el diseño de biorrefinerías que incluyan lignina pirolítica para la obtención de productos. (Texto tomado de la fuente)spa
dc.description.curricularareaÁrea curricular de Ingeniería Química e Ingeniería de Petróleosspa
dc.description.degreelevelDoctoradospa
dc.description.degreenameDoctor en Ingenieríaspa
dc.description.researchareaValorization of the pyrolytic ligninspa
dc.description.researchareaValorización de la lignina pirolíticaspa
dc.description.sponsorshipWorld Bankspa
dc.format.extentxviii, 96 páginas + 1 Anexospa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/83957
dc.language.isoengspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Medellínspa
dc.publisher.facultyFacultad de Minasspa
dc.publisher.placeMedellín, Colombiaspa
dc.publisher.programMedellín - Minas - Doctorado en Ingeniería - Sistemas Energéticosspa
dc.relation.indexedRedColspa
dc.relation.indexedLaReferenciaspa
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dc.relation.references[164] M. Gholizadeh et al., “Different reaction behaviours of the light and heavy components of bio-oil during the hydrotreatment in a continuous pack-bed reactor,” Fuel Processing Technology, vol. 146, pp. 76–84, Jun. 2016, doi: 10.1016/j.fuproc.2016.01.026.spa
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dc.relation.references[166] L. M. Balster, S. Zabarnick, R. C. Striebich, L. M. Shafer, and Z. J. West, “Analysis of polar species in jet fuel and determination of their role in autoxidative deposit formation,” Energy and Fuels, vol. 20, no. 6, pp. 2564–2571, Nov. 2006, doi: 10.1021/ef060275l.spa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseReconocimiento 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/spa
dc.subject.ddc660 - Ingeniería química::661 - Tecnología de químicos industrialesspa
dc.subject.ddc660 - Ingeniería química::662 - Tecnología de explosivos, combustibles, productos relacionadosspa
dc.subject.lembPirólisisspa
dc.subject.lembHidrogenaciónspa
dc.subject.lembHydrogenationeng
dc.subject.lembPyrolysiseng
dc.subject.proposalPyrolysis bio-oileng
dc.subject.proposalPyrolytic lignineng
dc.subject.proposalOligomerseng
dc.subject.proposalStructureseng
dc.subject.proposalFractionationeng
dc.subject.proposalBio-oil upgradingeng
dc.subject.proposalBioaceite de pirólisisspa
dc.subject.proposalLignina pirolíticaspa
dc.subject.proposalOligómerosspa
dc.subject.proposalEstructurasspa
dc.subject.proposalFraccionamientospa
dc.subject.proposalMejoramiento del bioaceitespa
dc.titleStudy of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment processeng
dc.title.translatedEstudio de la interacción entre los oligómeros de la fracción pesada del bioaceite de pirólisis rápida y un catalizador en el proceso de hidrotratamientospa
dc.typeTrabajo de grado - Doctoradospa
dc.type.coarhttp://purl.org/coar/resource_type/c_db06spa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentDataPaperspa
dc.type.driverinfo:eu-repo/semantics/doctoralThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TDspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentPúblico generalspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.awardtitleStudy of the interaction between the oligomers from bio-oil heavy fraction and a catalyst in hydrotreatment process - Contract number FP44842-210-2018spa
oaire.fundernameCall 788 of Minciencias Scientific Ecosystemspa

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