Análisis del desempeño puzolánico de las zeolitas naturales pre tratadas como adición al cemento Portland ordinario
| dc.contributor.advisor | Restrepo-Baena, Oscar Jaime | spa |
| dc.contributor.advisor | Tobon, Jorge Ivan | spa |
| dc.contributor.author | Flórez-Vergara, Cristian Andrés | spa |
| dc.contributor.researchgroup | Grupo del Cemento y Materiales de Construcción | spa |
| dc.date.accessioned | 2020-05-08T22:40:23Z | spa |
| dc.date.available | 2020-05-08T22:40:23Z | spa |
| dc.date.issued | 2019-11-11 | spa |
| dc.description.abstract | In this research, the effects of calcination and conventional grinding, individually and as a combination of pre-treatments, on the pozzolanic activity of natural zeolites were analyzed and evaluated. The characterization of the material was done by techniques such as fluorescence and X-ray diffraction, thermogravimetric analysis, particle sizes, specific surface area and porosity. Calcination was performed at 300, 600 and 800 ° C for a period of 5 hours. Conventional grinding was carried out to raw zeolites and after calcination in a ceramic ball mill for a period of 3 hours. Pastes and mortars with replacement percentages of 30, 40 and 50 % were prepared for the purpose of evaluating the pozzolanic activity, the mechanical strengths and the reaction rate of the natural zeolite type mordenite and heulandite-clinoptilolite present in the material. It was found that the pozzolanic activity of the natural zeolites increases for each pre-treatment separately and together after 8 days of hydration. The most effective individual pretreatment was grinding, but pretreatments as a combination bring many benefits such as the higher increase in compressive strength and non-agglomeration of the material in the mills. (Tomado de la fuente) | spa |
| dc.description.abstract | En esta investigación se analizaron y evaluaron los efectos que tienen la calcinación y la molienda convencional, de manera individual y como una combinación de pre-tratamientos en la actividad puzolánica de las zeolitas naturales. La caracterización del material se hizo mediante técnicas como la fluorescencia y difracción de rayos X, análisis termogravimétricos, granulometrías, área superficial específica y porosidad. Se realizaron calcinaciones a 300, 600 y 800 °C por un tiempo de 5 horas. La molienda convencional se efectuó, a las zeolitas crudas y posteriormente a la calcinación, en un molino cerámico de bolas por un tiempo de 3 horas. Se prepararon pastas y morteros con porcentajes de sustitución del 30, 40 y 50 % con el propósito de evaluar la actividad puzolánica, las resistencias mecánicas y la velocidad de reacción de las zeolitas naturales tipo mordenita y heulandita – clinoptilolita presentes en el material. Se encontró que la actividad puzolánica de las zeolitas naturales incrementa para cada pre-tratamiento por separado y en conjunto a partir de los 8 días de hidratación. El pretratamiento individual más efectivo fue la molienda, pero los pretratamientos en conjunto traen muchos beneficios como el incremento más alto en la resistencia a la compresión y el no empastamiento del material en los molinos. (Tomado de la fuente) | spa |
| dc.description.degreelevel | Maestría | spa |
| dc.description.degreename | Magíster en Ingeniería Recursos Minerales | |
| dc.format.extent | 93 | spa |
| dc.format.mimetype | application/pdf | spa |
| dc.identifier.instname | Universidad Nacional de Colombia | spa |
| dc.identifier.reponame | Repositorio Institucional Universidad Nacional de Colombia | spa |
| dc.identifier.repourl | https://repositorio.unal.edu.co/ | spa |
| dc.identifier.uri | https://repositorio.unal.edu.co/handle/unal/77498 | |
| dc.language.iso | spa | spa |
| dc.publisher.branch | Universidad Nacional de Colombia - Sede Medellín | spa |
| dc.publisher.department | Departamento de Materiales y Minerales | spa |
| dc.publisher.faculty | Facultad de Minas | spa |
| dc.publisher.place | Medellín | spa |
| dc.publisher.program | Medellín - Minas - Maestría en Ingeniería - Recursos Minerales | spa |
| dc.relation.references | W. S. Wise and C. Santa, “Structure of Zeolites,” Encyclopedia of Geology. pp. 591–600, 2005. | spa |
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| dc.relation.references | T. Wang, “U.S. and world cement production 2010 - 2018,” 2019. [Online]. Available: http://www.statista.com/statistics/219343/cementproductionworldwide/. [Accessed: 03-Sep-2019]. | spa |
| dc.relation.references | M. Garside, “Global cement production top countries 2018,” 2019. [Online]. Available: https://www.statista.com/statistics/267364/world-cement-production-by-country/. [Accessed: 03-Sep-2019]. | spa |
| dc.relation.references | P. A. Claisse, “Introduction to cement and concrete,” in Civil Engineering Materials, Elsevier, 2016, pp. 155–162. | spa |
| dc.relation.references | ASTM C 311-04, “Standard Test Methods for Sampling and Testing Fly Ash or Natural Pozzolans for Use in Portland-Cement Concrete.,” Annual Book of ASTM Standards, vol. 04.02. pp. 204–212, 2005. | spa |
| dc.relation.references | B. Uzal, L. Turanli, H. Yücel, M. C. Göncüoǧlu, and A. Çulfaz, “Pozzolanic activity of clinoptilolite: A comparative study with silica fume, fly ash and a non-zeolitic natural pozzolan,” Cem. Concr. Res., vol. 40, no. 3, pp. 398–404, 2010 | spa |
| dc.relation.references | Č. R. & I. E. Rahhal. V, Pavlík. Z, Tironi. A, Castellano. C, Trezza. M, “Effect of cement composition on the early hydration of blended cements with natural zeolite,” J. Therm. Anal. Calorim., vol. 128, 2017.. | spa |
| dc.relation.references | B. Uzal and L. Turanli, “Blended cements containing high volume of natural zeolites: Properties, hydration and paste microstructure,” Cem. Concr. Compos., vol. 34, no. 1, pp. 101–109, 2012 | spa |
| dc.relation.references | Y. Kocak, E. Tasci, and U. Kaya, “The effect of using natural zeolite on the properties and hydration characteristics of blended cements,” Constr. Build. Mater., vol. 47, pp. 720–727, 2013. | spa |
| dc.relation.references | E. Küçükyildirim and B. Uzal, “Characteristics of calcined natural zeolites for use in high-performance pozzolan blended cements,” Constr. Build. Mater., vol. 73, pp. 229–234, 2014. | spa |
| dc.relation.references | S. Seraj, R. D. Ferron, and M. C. G. Juenger, “Calcining natural zeolites to improve their effect on cementitious mixture workability,” Cem. Concr. Res., vol. 85, pp. 102–110, 2016. | spa |
| dc.relation.references | P. A. Zielinski, A. Van Neste, D. B. Akolekar, and S. Kaliaguine, “Effect of high-energy ball milling on the structural stability, surface and catalytic properties of small-, medium-and large-pore zeolites,” Microporous Mater., vol. 5, pp. 123–133, 1995. | spa |
| dc.relation.references | M. H. Cornejo, J. Elsen, C. Paredes, and H. Baykara, “Thermomechanical treatment of two Ecuadorian zeolite-rich tuffs and their potential usage as supplementary cementitious materials,” J. Therm. Anal. Calorim., vol. 115, no. 1, pp. 309–321, Jan. 2014. | spa |
| dc.relation.references | G. Cruciani, “Zeolites upon heating: Factors governing their thermal stability and structural changes,” J. Phys. Chem. Solids, vol. 67, pp. 1973–1994, 2006. | spa |
| dc.relation.references | ASTM C1157 / C1157M-11, “Standard Performance Specification for Hydraulic Cement,” ASTM Int., pp. 1–5, 2011 | spa |
| dc.relation.references | M. N. Mohammad Shekarchi, Babak Ahmadi, “Use of Natural Zeolite as Pozzolanic Material in Cement and Concrete Composites,” in Handbook of Natural Zeolites, 2012 | spa |
| dc.relation.references | K. S. W. SING et al., “REPORTING PHYSISORPTION DATA FOR GAS/SOLID SYSTEMS with Special Reference to the Determination of Surface Area and Porosity,” Int. UNION PURE Appl. Chem., vol. 57, pp. 603–619, 1985. | spa |
| dc.relation.references | ASTM C618, “Standard specification for coal fly ash and raw or calcined natural pozzolona for use in concrete.” p. 5, 2015. | spa |
| dc.relation.references | W. Devices, “Standard Test Method for Compressive Strength of Hydraulic Cement Mortars,” vol. 04, no. May, pp. 1–6, 1999. | spa |
| dc.rights | Derechos reservados - Universidad Nacional de Colombia | spa |
| dc.rights.accessrights | info:eu-repo/semantics/openAccess | spa |
| dc.rights.license | Atribución-SinDerivadas 4.0 Internacional | spa |
| dc.rights.license | Atribución-SinDerivadas 4.0 Internacional | spa |
| dc.rights.spa | Acceso abierto | spa |
| dc.rights.uri | http://creativecommons.org/licenses/by-nd/4.0/ | spa |
| dc.subject.ddc | 550 - Ciencias de la tierra::551 - Geología, hidrología, meteorología | spa |
| dc.subject.proposal | Natural zeolites | eng |
| dc.subject.proposal | Zeolitas naturales, | spa |
| dc.subject.proposal | Pozzolanic activity | eng |
| dc.subject.proposal | Actividad puzolánica | spa |
| dc.subject.proposal | Supplementary cementitious materials | eng |
| dc.subject.proposal | Materiales cementantes suplementarios | spa |
| dc.subject.proposal | Calcinación | spa |
| dc.subject.proposal | Calcination | eng |
| dc.subject.proposal | Conventional milling | eng |
| dc.subject.proposal | Molienda convencional | spa |
| dc.title | Análisis del desempeño puzolánico de las zeolitas naturales pre tratadas como adición al cemento Portland ordinario | spa |
| dc.title.translated | Analysis of pozzolanic performance of pretreated natural zeolites as an addition to ordinary Portland cement. | eng |
| dc.type | Trabajo de grado - Maestría | spa |
| dc.type.coar | http://purl.org/coar/resource_type/c_bdcc | spa |
| dc.type.coarversion | http://purl.org/coar/version/c_ab4af688f83e57aa | spa |
| dc.type.content | Text | spa |
| dc.type.driver | info:eu-repo/semantics/masterThesis | spa |
| dc.type.version | info:eu-repo/semantics/acceptedVersion | spa |
| oaire.accessrights | http://purl.org/coar/access_right/c_abf2 | spa |
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