Compuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacteriana

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dc.contributor.advisorPabón Gelves, Elizabeth
dc.contributor.advisorMuñoz Acevedo, Juan Carlos
dc.contributor.authorMúnera Gómez, Luisa Fernanda
dc.contributor.cvlacMúnera Gómez, Luisa Fernanda [0001949499]spa
dc.contributor.orcidMúnera Gómez, Luisa [0009-0006-3097-2849]spa
dc.contributor.researchgroupCiencia de Materiales Avanzadosspa
dc.date.accessioned2024-01-30T16:50:48Z
dc.date.available2024-01-30T16:50:48Z
dc.date.issued2023-12
dc.descriptionIlustracionesspa
dc.description.abstractLos compuestos de coordinación con ligandos orgánicos de interés biológico han demostrado tener actividad antibacteriana ante una gran variedad de géneros entre los que se incluyen algunas bacterias resistentes a los tratamientos convencionales. Los aminoácidos son un grupo de moléculas muy versátiles con dos grupos funcionales (amino y carboxilo), esto favorece la interacción con el metal permitiendo sintetizar compuestos con alto potencial antibacteriano. En esta tesis se sintetizaron por métodos convencionales compuestos de coordinación con los metales divalente cobre y níquel, y se usaron como ligandos los aminoácidos glicina, alanina y los ácidos dicarboxílicos itacónico y oxálico. La caracterización de los compuestos sintetizados se realizó por análisis termogravimétrico (TGA), espectroscopia infrarroja por transformada de Fourier (FTIR), espectroscopia ultravioleta - visible (UV-vis) y difracción de rayos X (DRX), mostrando que los compuestos son octaédricos, cristalinos y estables a temperaturas entre los 250 a 300°C. Además, estos compuestos mostraron buena actividad antibacteriana principalmente contra cepas gram-positivas, esto se comprobó por el método del halo de inhibición y mediante la determinación de la concentración mínima inhibitoria la cual fue de 20 ppm para los compuestos con cobre y para los compuestos con níquel estuvo entre 10 y 5 ppm. (texto tomado de la fuente)spa
dc.description.abstractCoordination compounds with organic ligands of biological interest have shown to have antibacterial activity against a wide variety of genera, including some bacteria resistant to conventional treatments. Amino acids are a group of very versatile molecules with two functional groups (amino and carboxyl), this favors the interaction with the metal, allowing the synthesis of compounds with high antibacterial potential. In this thesis, coordination compounds with the divalent metals copper and nickel were synthesized by conventional methods, and the amino acids glycine, alanine, and the dicarboxylic acids itaconic and oxalic acids were used as ligands. The characterization of the synthesized compounds was carried out by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), ultraviolet - visible spectroscopy (UV-vis) and X-ray diffraction (XRD), showing that the compounds are octahedral, crystalline and stable at temperatures between 250 to 300°C. In addition, these compounds showed good antibacterial activity mainly against gram-positive strains, this was verified by the inhibition zone method and by determining the minimum inhibitory concentration which was 20 ppm for the compounds with copper and for the compounds with Nickel was between 10 and 5 ppm.eng
dc.description.curricularareaÁrea Curricular en Ciencias Naturalesspa
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ciencias - Químicaspa
dc.format.extent100 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/85529
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Medellínspa
dc.publisher.facultyFacultad de Cienciasspa
dc.publisher.placeMedellín, Colombiaspa
dc.publisher.programMedellín - Ciencias - Maestría en Ciencias - Químicaspa
dc.relation.indexedLaReferenciaspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.subject.ddc540 - Química y ciencias afines::546 - Química inorgánicaspa
dc.subject.ddc540 - Química y ciencias afines::547 - Química orgánicaspa
dc.subject.lembAminoácidos
dc.subject.lembCompuestos de coordinación
dc.subject.proposalCompuestos de coordinaciónspa
dc.subject.proposalCoordination compoundseng
dc.subject.proposalActividad antibacterianaspa
dc.subject.proposalAntibacterial activityeng
dc.subject.proposalAminoácidosspa
dc.subject.proposalAmino acidseng
dc.subject.proposalGlicinaspa
dc.subject.proposalGlycineeng
dc.subject.proposalAlaninaspa
dc.subject.proposalAlanineeng
dc.subject.proposalMetáles divalentesspa
dc.subject.proposalDivalent metalseng
dc.subject.proposalÁcidos dicarboxílicosspa
dc.subject.proposalDicarboxylic acidseng
dc.subject.proposalConcentración mínima inhibitoriaspa
dc.subject.proposalMinimum inhibitory concentrationeng
dc.subject.wikidataGlicina
dc.subject.wikidataAlanina
dc.titleCompuestos de coordinación de metales divalentes con aminoácidos y ácidos dicarboxílicos: potencial actividad antibacterianaspa
dc.title.translatedCoordination compounds of divalent metals with amino acids and dicarboxylic acids: potential antibacterial activityeng
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
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dc.type.driverinfo:eu-repo/semantics/masterThesisspa
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dcterms.audience.professionaldevelopmentMaestrosspa
dcterms.audience.professionaldevelopmentPúblico generalspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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