C1 biorefineries : The CO2 case

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dc.contributor.advisorCardona Alzate, Carlos Ariel
dc.contributor.authorInocencio García, Pablo José
dc.contributor.cvlacInocencio-García, Pablo-José [https://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001996470]spa
dc.contributor.googlescholarInocencio-García, Pablo-José [https://scholar.google.com/citations?user=tR1yZp8AAAAJ&hl=es]spa
dc.contributor.orcidInocencio-García, Pablo-José [https://orcid.org/000900036684330X]spa
dc.contributor.researchgateInocencio-García, Pablo-José [https://www.researchgate.net/profile/Pablo-Inocencio-Garcia]spa
dc.contributor.researchgroupProcesos Químicos Cataliticos y Biotecnológicosspa
dc.contributor.scopusInocencio-García, Pablo-José [https://www.scopus.com/authid/detail.uri?authorId=58162518900]spa
dc.date.accessioned2025-03-18T16:26:59Z
dc.date.available2025-03-18T16:26:59Z
dc.date.issued2024
dc.descriptiongraficas, ilustracionesspa
dc.description.abstractCarbon dioxide (CO2) emissions have caused a significant impact on climate change and global warming, with concentrations reaching 400 ppm in recent years. Various technologies exist for CO2 capture and utilization (CCU) in industrial facilities known as C1 biorefineries where CO2 is considered a raw material in the obtaining of various products, achieving a reduction in greenhouse gases (GHG) emissions. Then, by considering the current interest in carbon upgrading technologies, this thesis project focuses on analyzing CCU alternatives under the C1 biorefinery concept. Initially, a heuristic analysis was performed to select the best CO2 capture technology (CCS) and to study the main products to be obtained from CO2 at each technological readiness level. Moreover, experiments were carried out to produce CO-rich syngas from biomass gasification with CO2, formic acid production by electrochemical CO2, and dimethyl carbonate (DMC) production under supercritical CO2 conditions. The results of the experimental approach served as a base point for the simulation of the processes. Two additional schemes for CO2 valorization were proposed under stand-alone schemes: production of methanol by hydrogenation of CO2, and ethanol production by utilization of CO2 through the CBB cycle of the cyanobacteria Synechococcus sp. PCC 7942. In addition, these technologies were analyzed under integration schemes of C1 biorefineries based on the global market distribution for each product. Then, the feasibility of the CO2 valorization schemes was assessed by considering technical, economic, environmental, and social performance indicators. The results showed that the implementation of CO2 valorization schemes for the production of CO-rich syngas under a stand-alone configuration is the most viable alternative for the Colombian context. In addition, the integration of these schemes under C1 biorefinery scenarios for the production of methanol, CO-rich synthesis gas, DMC, and formic acid also showed viability in the four dimensions contemplated in the sustainability analysis (Texto tomado de la fuente).eng
dc.description.abstractLas emisiones de dióxido de carbono (CO2) han causado un impacto significativo en el cambio climático y el calentamiento global, con concentraciones que alcanzan las 400 ppm en los últimos años. Existen diversas tecnologías para captura y utilización (CCU) del CO2 en instalaciones industriales conocidas como biorrefinerías C1, donde el CO2 se considera como materia prima en la obtención de diversos productos logrando una reducción en las emisiones de gases de efecto invernadero (GEI). En consecuencia, al considerar el interés actual en las tecnologías de aprovechamiento del carbono, esta tesis se centra en analizar las distintas alternativas de CCU bajo el concepto de biorrefinería C1. Inicialmente, se realizó un análisis heurístico para seleccionar la mejor tecnología de captura de CO2 (CCS) y estudiar los principales productos que se pueden obtener a partir del CO2 en cada nivel de madurez tecnológica. Además, se llevaron a cabo experimentos para producir gas de síntesis rico en CO a partir de la gasificación de biomasa con CO2, producción de ácido fórmico mediante reducción electroquímica CO2, y producción de dimetil carbonato (DMC) en condiciones supercríticas de CO2. Los resultados del enfoque experimental sirvieron como punto de base para la simulación de los procesos. Además, se propusieron dos esquemas adicionales para la valorización del CO2 bajo esquemas stand-alone: producción de metanol por hidrogenación de CO2 y producción de etanol mediante la utilización de CO2 a través del ciclo CBB de la cianobacteria Synechococcus sp. PCC 7942. Estas tecnologías se analizaron bajo esquemas de integración de biorrefinerías C1 propuestos con base en la distribución del mercado global para cada producto. Posteriormente, se evaluó la viabilidad de cada esquema de valorización considerando indicadores de desempeño de las dimensiones técnica, económica, ambiental y social. Los resultados demostraron que la implementación de esquemas de valorización de CO2 para la producción de gas de síntesis enriquecido en CO bajo configuración stand-alone, es la alternativas más viable para el contexto colombiano. Además, la integración de estos esquemas bajo escenarios de biorrefinerías C1 para la producción de metanol, gas de síntesis rico en CO, DMC, y ácido fórmico también presentó viabilidad en las cuatro dimensiones contempladas en el análisis de sostenibilidad.spa
dc.description.curricularareaQuímica Y Procesos.Sede Manizalesspa
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ingeniería - Ingeniería Químicaspa
dc.format.extentvii, 198 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/87684
dc.language.isoengspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Manizalesspa
dc.publisher.facultyFacultad de Ingeniería y Arquitecturaspa
dc.publisher.placeManizales, Colombiaspa
dc.publisher.programManizales - Ingeniería y Arquitectura - Maestría en Ingeniería - Ingeniería Químicaspa
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dc.subject.ddc660 - Ingeniería químicaspa
dc.subject.proposalCarbon dioxideeng
dc.subject.proposalCarbon Capture and Utilizationeng
dc.subject.proposalC1 biorefinerieseng
dc.subject.proposalCarbon neutralityeng
dc.subject.proposalCircular economyeng
dc.subject.proposalTechno-economic assessmenteng
dc.subject.proposalLife cycle assessmenteng
dc.subject.proposalSustainabilityeng
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dc.subject.proposalCaptura y utilización de carbonospa
dc.subject.proposalBiorrefinerías C1spa
dc.subject.proposalNeutralidad de carbonospa
dc.subject.proposalEconomía circularspa
dc.subject.proposalEvaluación tecno-económicaspa
dc.subject.proposalEvaluación del ciclo de vidaspa
dc.subject.proposalSostenibilidadspa
dc.subject.unescoSostenibilidadspa
dc.subject.unescoImpacto ambientalspa
dc.titleC1 biorefineries : The CO2 caseeng
dc.title.translatedBiorrefinerías C1 : El caso del CO2spa
dc.typeTrabajo de grado - Maestríaspa
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oaire.fundernameUniversidad de Sucrespa

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