Producción, caracterización y resistencia a la corrosión de recubrimientos de TiAlZrTaNbN con potencial aplicación en la industria Biomédica e Industrial

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dc.contributor.advisorOlaya Florez, Jhon Jairospa
dc.contributor.authorGonzalez Avila, Ingrid Johanaspa
dc.contributor.other(Piamba Tulcan, Oscar Edwin)spa
dc.contributor.researchgroupGrupo de Investigación en Corrosión, Tribologia y Energíaspa
dc.date.accessioned2025-07-02T19:50:13Z
dc.date.available2025-07-02T19:50:13Z
dc.date.issued2024-08-21
dc.description.abstractEl objeto de estudio de esta investigación son los recubrimientos de nitruro de TiAlZrTaNb sobre la superaleación Haynes 282 y la aleación de Ti6Al4V, los cuales fueron depositados mediante la técnica de pulverización catódica con magnetrón por impulso de alta potencia (HiPIMS) con una variación de la polarización del sustrato de 0 V a −75 V y una presión de trabajo de 0,3 Pa a 0,7 Pa. Se investigó el efecto de la polarización del voltaje de sustrato Bias y la presión de trabajo sobre la resistencia a la corrosión mediante métodos electroquímicos en las películas. La microestructura, morfología y composición química de los recubrimientos se analizaron mediante difracción de rayos X, microscopía electrónica de barrido y espectroscopía de rayos X de energía dispersiva. La porosidad de la muestra y la resistencia a la corrosión se caracterizaron mediante métodos electroquímicos, en específico, a partir de pruebas de impedancia electroquímica (EIS) y de polarización potenciodinámica empleando una solución de NaCl al 3,5 % en peso y suero fisiológico. Los resultados sugieren que las películas pueden ser consideradas como aleaciones de alta entropía, nanoestructuradas, policristalinas y que su resistencia a la corrosión es afectada principalmente por la presión de trabajo en la cámara. Por último, se describe el mecanismo de corrosión en las películas depositadas sobre cada uno de los sustratos. (Texto tomado de la fuente)spa
dc.description.abstractThe object of study of this research is the TiAlZrTaNb nitride coatings on the Haynes 282 superalloy and the Ti6Al4V alloy, which were deposited using the high-power impulse magnetron sputtering technique (HiPIMS), applying a variation of the substrate bias from 0 V to −75 V and a working pressure from 0,3 Pa to 0,7 Pa. The effect of substrate voltage Bias and working pressure on corrosion resistance was investigated by electrochemical methods on the films. The microstructure, morphology and chemical composition of the coatings were analyzed by X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. The porosity of the sample and the corrosion resistance were characterized by electrochemical methods, specifically, with electrochemical impedance (EIS) and potentiodynamic polarization tests using a 3.5 wt % NaCl solution and physiological saline. The results suggest that the films can be considered as high entropy, nanostructured, polycrystalline alloys and that their corrosion resistance is mainly affected by the working pressure in the chamber. Finally, the corrosion mechanism in the films deposited on each of the substrates is describedeng
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Materiales y procesosspa
dc.description.researchareaIngeniería de superficiespa
dc.format.extent121 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/88274
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Ingenieríaspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ingeniería - Maestría en Ingeniería - Materiales y Procesosspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.subject.ddc620 - Ingeniería y operaciones afinesspa
dc.subject.lembCorrosión del aluminiospa
dc.subject.lembAluminum - corrosioneng
dc.subject.proposalHiPIMSeng
dc.subject.proposalSuperaleaciónspa
dc.subject.proposalAleaciones de alta entropíasspa
dc.subject.proposalNitruros de alta entropíaspa
dc.subject.proposalCorrosiónspa
dc.subject.proposalHigh entropy alloyseng
dc.subject.proposalHigh entropy nitrideseng
dc.subject.proposalCorrosioneng
dc.subject.proposalSuperalloyeng
dc.subject.wikidataAleaciones de aluminiospa
dc.subject.wikidataNitruro de titanio aluminiospa
dc.subject.wikidataAluminium alloyeng
dc.subject.wikidataTitanium aluminium nitrideeng
dc.titleProducción, caracterización y resistencia a la corrosión de recubrimientos de TiAlZrTaNbN con potencial aplicación en la industria Biomédica e Industrialspa
dc.title.translatedProduction, characterization and corrosion resistance of TiAlZrTaNbN coatings with potential application in the biomedical and industrial industrieseng
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentEstudiantesspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
dcterms.audience.professionaldevelopmentPersonal de apoyo escolarspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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