Evaluación de la resistencia a la corrosión de recubrimientos de TiB2 depositados sobre Ti y Ti-6Al-4V obtenidos mediante la técnica de láser cladding coaxial

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dc.contributor.advisorAngarita Moncaleano, Irma Inirida
dc.contributor.advisorOlaya Florez, Jhon Jairo
dc.contributor.authorAgredo Diaz, Dayi Giberto
dc.contributor.googlescholarhttps://scholar.google.es/citations?user=SkA2vycAAAAJ&hl=esspa
dc.contributor.orcidAgredo Diaz, Dayi Gilberto [0000-0003-2830-3022]spa
dc.contributor.researchgroupGrupo de Investigación Afis (Análisis de Fallas, Integridad y Superficies)spa
dc.contributor.researchgroupGrupo de Investigación en Corrosión, Tribologia y Energíaspa
dc.date.accessioned2023-01-17T16:33:04Z
dc.date.available2023-01-17T16:33:04Z
dc.date.issued2022
dc.descriptionilstraciones, fotografías, graficasspa
dc.description.abstractEl titanio es un material altamente utilizado en la industria, condición ligada a sus buenas propiedades, sin duda alguna esto ofrece ventajas importantes con respecto a materiales como el acero; es así que las industrias de mayor demanda son la aeronáutica, medica, industria armamentista e incluso en el ámbito deportivo. En esta investigación se sintetizan recubrimientos metal-cerámica (60% wt de Ti+ 40% wt de TiB2) por la técnica de láser cladding coaxial sobre sustratos de Ti grado 2 y Ti-6Al-4V a diferentes niveles de energía (600, 900 y 1000 W) y se evalúa su comportamiento electroquímico en una solución de NaCl al 3.5% y a alta temperatura. Se caracteriza el material por microscopia electrónica de barrido, la evaluación electroquímica se hace por medio de espectroscopia de impedancia y polarización tafel, su estructura se evalúa por difracción de rayos X. La corrosión a alta temperatura es evaluada por medio de la técnica de oxidación cíclica. A nivel electroquímico los resultados muestran que los recubrimientos modifican la respuesta electroquímica del sistema, brindando protección sobre la superficie del material, lo cual está asociado a la formación de una capa protectora sobre la superficie del material (formación de compuestos de TiB, TiB2, TiO2; en la corrosión a alta temperatura se encuentra reducción de la degradación del material recubierto a diferencia del material sin recubrimiento, evidenciando la formación de compuestos principalmente constituidos por TiO2 (Texto tomado de la fuente).spa
dc.description.abstractTitanium is a highly used material in the industry, a condition linked to its good properties, without a doubt this offers important advantages with respect to materials such as steel; Thus, the industries with the greatest demand are aeronautics, medicine, the arms industry and even sports. In this research, metal-ceramic coatings (60% wt Ti+ 40% wt TiB2) are synthesized using the coaxial laser cladding technique on Ti grade 2 and Ti-6Al-4V substrates at different energy levels (600, 900 and 1000 W) and its electrochemical behavior is evaluated in a 3.5% NaCl solution and at high temperature. The material is characterized by scanning electron microscopy, the electrochemical evaluation is done by means of impedance spectroscopy and tafel polarization, its structure is evaluated by X-ray diffraction. Corrosion at high temperature is evaluated using of the cyclic oxidation technique. At an electrochemical level, the results show that the coatings modify the electrochemical response of the system, providing protection on the surface of the material, which is associated with the formation of a protective layer on the surface of the material (formation of compounds of TiB, TiB2, TiO2; in high-temperature corrosion, a reduction in the degradation of the coated material is found, unlike the uncoated material, evidencing the formation of compounds mainly constituted by TiO2.eng
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ingeniería - Materiales y Procesosspa
dc.description.researchareaIngenieria de superficiesspa
dc.format.extentxvii, 107 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/82981
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Ingenieríaspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ingeniería - Maestría en Ingeniería - Materiales y Procesosspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseReconocimiento 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/spa
dc.subject.ddc660 - Ingeniería química::669 - Metalurgiaspa
dc.subject.lembTITANIOspa
dc.subject.lembTitaniumeng
dc.subject.lembMATERIALES RESISTENTES A LA CORROSIONspa
dc.subject.lembCorrosion resistant materialseng
dc.subject.proposalTi-6Al-4Vspa
dc.subject.proposalLáser cladding coaxialspa
dc.subject.proposalRecubrimientos cerámicos por láserspa
dc.subject.proposalCorrosión electroquímicaspa
dc.subject.proposalOxidación cíclicaspa
dc.subject.proposalTi-6Al-4Veng
dc.subject.proposalCoaxial Laser Claddingeng
dc.subject.proposalLaser Ceramic Coatingseng
dc.subject.proposalElectrochemical Corrosioneng
dc.subject.proposalCyclic Oxidationeng
dc.titleEvaluación de la resistencia a la corrosión de recubrimientos de TiB2 depositados sobre Ti y Ti-6Al-4V obtenidos mediante la técnica de láser cladding coaxialspa
dc.title.translatedEvaluation of the corrosion resistance of TiB2 coatings deposited on Ti and Ti-6Al-4V obtained using coaxial laser cladding techniqueeng
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentEstudiantesspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
dcterms.audience.professionaldevelopmentPúblico generalspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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