Alternativas de Aprovechamiento del Glicerol
| dc.contributor.advisor | Romero Malagón, Eduard Ricardo | spa |
| dc.contributor.author | Usme Contreras, Juan Diego | spa |
| dc.contributor.researchgroup | LABORATORIO DE INVESTIGACIÓN EN COMBUSTIBLES Y ENERGÍA | spa |
| dc.date.accessioned | 2021-01-27T19:56:36Z | spa |
| dc.date.available | 2021-01-27T19:56:36Z | spa |
| dc.date.issued | 2020-08-10 | spa |
| dc.description.abstract | Glycerol by-product of biodiesel manufacturing has increased consequence of the high use of biofuels on the last 30 years. Likewise, Colombia has 12 biodiesel plants which produce more than 480 KT of biofuel per year, and according to the esterification reaction proportion, raw glycerin occupies 10% such all production. Because this scenario, the internationally manufacture of USP glycerol from propene was suspended, instead to produce epichlorohydrin (epoxy resins precursor) from glycerol. Along with this glycerol derivative, the reaction conditions, and applications of value chemicals such as glycerin ethers and esters (GTBE and acetins), methanol, methane, acrolein, 1,3-propanediol, tartronic acid, glyceric acid, mesoxalic acid, dihydroxyacetone and glycerol carbonate are explored. Glycerol derivatives were categorized into three groups according to their level of industrial development, country background, economic aspects (value per Kg, market size, amount estimate investment for the projected application) to choose industrial potential reactions satisfy green chemistry principles: esterification with 5% sulfonated carbonized at 115°C, 1 h, with 4:1 AcOH/glycerol and 1:1 Ac2O/glycerol for 30 with 100% triacetin yield; FePO4-mediated dehydration at 280°C, 5 h, 0.40 glycerol/H2O with 92% acrolein yield and transesterification-carbonylation with 0.10 CaO/glycerol at 75°C, 90 min, 1:1 DMC to produce 95% glycerol carbonate yield. | spa |
| dc.description.abstract | En los últimos 30 años como consecuencia del crecimiento del uso de biocombustibles. Colombia posee 12 plantas La producción de glicerol subproducto de la fabricación de biodiesel se ha incrementado de biodiesel que producen más de 480 KT anuales del biocombustible y de acuerdo con la proporción de la reacción de esterificación, la glicerina cruda ocupa el 10% de la totalidad de la producción. Dado que no es posible dar un uso a tal cantidad de glicerina, a pesar de sus diversas aplicaciones en este documento se hace énfasis en analizar las investigaciones realizadas en relación con las síntesis de compuestos derivados del glicerol que tienen aplicaciones con valor comercial como los éteres y ésteres de glicerina (GTBE y acetinas), metanol, metano, acroleína, 1,3-propanodiol ácido tartrónico, ácido glicérico, ácido mesoxálico, dihidroxiacetona y carbonato de glicerol. Se categorizaron los derivados del glicerol en tres grupos según su nivel de explotación industrial, los antecedentes de uso en el país, los aspectos económicos (valor/kg del tamaño del mercado, la inversión estimada y la magnitud económica de la aplicación proyectada) para la elección de las siguientes reacciones químicas con potencial industrial incluyendo criterios de la química verde: La esterificación con 5% carbonizado sulfonado a 115°C, 1 h, con 4:1 AcOH/glicerol y 1:1 Ac2O/glicerol por 30 min obteniendo 100% de triacetina; La deshidratación con FePO4 a 280°C, 5 h, 0,40 glicerol/H2O para obtener 92% de acroleína y, La transesterificación-carbonilación con 0,10 CaO/glicerol a 75°C, 90 min, 3:1 DMC/glicerol logrando 95% de carbonato de glicerol.. | spa |
| dc.description.additional | Línea de investigación: Materiales y energía Trabajo aceptado en agosto de 2020 por el programa curricular del departamento de Química, Facultad de Ciencias, sede Bogotá. Realización de Socialización de este Trabajo Final de Maestría en Ciencias Química el 23 de Octubre 2020 aprobatorio. | spa |
| dc.description.degreelevel | Maestría | spa |
| dc.format.extent | 114 | spa |
| dc.format.mimetype | application/pdf | spa |
| dc.identifier.citation | Usme , C., Juan D. (2020) Alternativas de Aprovechamiento del Glicerol. Universidad Nacional de Colombia - Sede Bogotá, Bogotá Colombia. | spa |
| dc.identifier.uri | https://repositorio.unal.edu.co/handle/unal/78946 | |
| dc.language.iso | spa | spa |
| dc.publisher.branch | Universidad Nacional de Colombia - Sede Bogotá | spa |
| dc.publisher.department | Departamento de Química | spa |
| dc.publisher.program | Bogotá - Ciencias - Maestría en Ciencias - Química | spa |
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| dc.rights | Derechos reservados - Universidad Nacional de Colombia | spa |
| dc.rights.accessrights | info:eu-repo/semantics/openAccess | spa |
| dc.rights.license | Atribución-NoComercial-SinDerivadas 4.0 Internacional | spa |
| dc.rights.spa | Acceso abierto | spa |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | spa |
| dc.subject.ddc | 540 - Química y ciencias afines | spa |
| dc.subject.proposal | Derivados del glicerol | spa |
| dc.subject.proposal | Glycerol derivatives | eng |
| dc.subject.proposal | Glycerol valorization | eng |
| dc.subject.proposal | Valorización de la glicerina | spa |
| dc.subject.proposal | Acetinas | spa |
| dc.subject.proposal | Acetins | eng |
| dc.subject.proposal | Carbonato de glicerol | spa |
| dc.subject.proposal | Glycerol carbonate | eng |
| dc.subject.proposal | Acroleína | spa |
| dc.subject.proposal | acrolein | eng |
| dc.title | Alternativas de Aprovechamiento del Glicerol | spa |
| dc.title.alternative | Glycerol Utilization Alternatives | spa |
| dc.type | Trabajo de grado - Maestría | spa |
| dc.type.coar | http://purl.org/coar/resource_type/c_bdcc | spa |
| dc.type.coarversion | http://purl.org/coar/version/c_ab4af688f83e57aa | spa |
| dc.type.content | Text | spa |
| dc.type.driver | info:eu-repo/semantics/masterThesis | spa |
| dc.type.version | info:eu-repo/semantics/acceptedVersion | spa |
| oaire.accessrights | http://purl.org/coar/access_right/c_abf2 | spa |