Síntesis y caracterización de derivados cumarín piridínicos y su aplicación en la detección de un ion metálico

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dc.contributor.advisorGranados Oliveros, Gilma
dc.contributor.authorSánchez Sierra, Christian Camilo
dc.contributor.researchgroupSíntesis Orgánica Sosteniblespa
dc.date.accessioned2023-08-08T21:50:59Z
dc.date.available2023-08-08T21:50:59Z
dc.date.issued2021-11-22
dc.descriptionilustraciones, diagramas
dc.description.abstractThree new and novel hybrids of coumarin pyridines with a donor π acceptor system were synthesized in a 5-step series, without metal catalysts or special experimental conditions. These compounds were characterized by melting point, IR-TF, 1H NMR, APT and 13C, UV-Vis spectroscopy and fluorescence. Also, mass spectrometry. The photophysical characteristics of the pyridine coumarin derivatives were studied, showing that they are strong emitters of blue light when excited at a λem of 300 nm, reaching quantum yields between 10 and 12%, these were evaluated against various metal ions, showing a high selectivity for Al3+. (Texto tomado de la fuente)eng
dc.description.abstractTres nuevos y novedosos híbridos de cumarín piridinas con un sistema donor π aceptor fueron sintetizados en una serie de 5 pasos, sin catalizadores metálicos, ni condiciones experimentales especiales. Estos compuestos fueron caracterizados por punto de fusión, IR-TF, RMN 1H, APT y 13C, espectroscopía de UV-Vis y fluorescencia. Además, de espectrometría de masas. Se estudiaron las características fotofísicas de los derivados cumarín piridínicos mostrando ser unos fuertes emisores de luz azul al ser excitados a una λem de 300 nm llegando a tener rendimientos cuánticos entre el 10 y 12 %, estos fueron evaluados frente a diversos iones metálicos, mostrando una alta selectividad por Al3+.spa
dc.description.degreelevelMaestríaspa
dc.description.researchareaQuímica Orgánica, supramolecularspa
dc.format.extent99 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/84501
dc.language.isospaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Administraciónspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ciencias - Maestría en Ciencias - Químicaspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseReconocimiento 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/spa
dc.subject.ddc540 - Química y ciencias afinesspa
dc.subject.lembCompuesto heterocíclicospa
dc.subject.lembHeterocyclic compoundseng
dc.subject.lembiones metálicosspa
dc.subject.lembMetal ionseng
dc.subject.proposalCumarinasspa
dc.subject.proposalPiridinasspa
dc.subject.proposalAl3+spa
dc.subject.proposalBase de Schiffspa
dc.subject.proposalQuimiosensorspa
dc.titleSíntesis y caracterización de derivados cumarín piridínicos y su aplicación en la detección de un ion metálicospa
dc.title.translatedSynthesis and characterization of coumarin pyridine derivatives and their application in the detection of a metal ioneng
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

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