Mejoramiento de la inyección de agua de baja salinidad mediante nanopartículas aplicado al recobro mejorado de petróleo

dc.contributor.advisorCortés Correa, Farid Bernardospa
dc.contributor.advisorFranco Ariza, Camilo Andrésspa
dc.contributor.authorCausil Loaiza, María Angélicaspa
dc.contributor.corporatenameUniversidad Nacional de Colombia - Sede Medellínspa
dc.contributor.researchgroupFenómenos de Superficie - Michael Polanyispa
dc.date.accessioned2020-03-17T20:15:00Zspa
dc.date.available2020-03-17T20:15:00Zspa
dc.date.issued2019-10-29spa
dc.description.abstractThe injection of water to oil fields is a technique that allows to increase the energy of this, favoring the efficiency of oil recovery. Although, water injection is one of the most used techniques, recently the use of low salinity water has had great scientific attention. However, the mechanisms by which this method works are still not completely clear. On the other hand, the use of nanotechnology in improved oil recovery processes has gained popularity due to the performance it has had in increasing oil production. In this paper, we intend to understand the mechanism of interaction in the crude / brine of low salinity / rock interfaces and in turn, improve the injection of low salinity water with nanoparticles that positively impact the interfacial properties. To achieve what was described, in a first stage of the work the surface-active components were extracted: asphaltenes, resins and naphthenic acids for the preparation of model solutions and evaluation of their effect on the interfacial film. Interfacial tension measurements were made model solution-water and contact angle of cores of varied mineralogical composition to estimate changes in interfacial tension and wettability. These measurements were also performed for dispersions of alumina nanoparticles (nanofluid) in low salinity water. When using the designed nanofluid, a change in the water-oil interfacial tension and contact angle was observed, in addition to a significant increase in oil recovery of 25 and 44% for systems in the absence and presence of nanoparticles, respectively.spa
dc.description.abstractLa inyección de agua a yacimientos de petróleo es una técnica que permite incrementar la energía de este, favoreciendo la eficiencia de recuperación de aceite. Aunque, la inyección de agua es una de las técnicas más usadas, recientemente el uso de agua de baja salinidad ha tenido una gran atención científica. No obstante, los mecanismos por los que este método funciona todavía no son completamente claros. Por otro lado, el uso de nanotecnología en los procesos de recuperación mejorada de crudo ha ganado popularidad debido al desempeño que ha tenido en el incremento de la producción de aceite. En el presente trabajo se pretende comprender el mecanismo de interacción en las interfases crudo/salmuera de baja salinidad/roca y a su vez, mejorar la inyección de agua baja de salinidad con nanopartículas que impacten positivamente las propiedades interfaciales. Para lograr lo descrito, en una primera etapa del trabajo se extrajeron los componentes activos superficiales: asfaltenos, resinas y ácidos nafténicos para la preparación de soluciones modelos y evaluación de su efecto en la película interfacial. Se realizaron mediciones de tensión interfacial soluciones modelo-agua y ángulo de contacto de núcleos de variada composición mineralógica para estimar los cambios en tensión interfacial y en mojabilidad. Estas medidas también se realizaron para dispersiones de nanopartículas de alúmina (nanofluido) en el agua de baja salinidad. Al utilizar el nanofluido diseñado se observó un cambio en la tensión interfacial agua-aceite y ángulo de contacto, además de un incremento importante en la recuperación de petróleo del 25 y 44% para los sistemas en ausencia y presencia de nanopartículas, respectivamente.spa
dc.description.additionalMagister en Medio Ambiente y Desarrollospa
dc.description.degreelevelMaestríaspa
dc.description.sponsorshipColciencias, ANH y Universidad Nacional de Colombia. Convenio 273-201spa
dc.format.extent82spa
dc.format.mimetypeapplication/pdfspa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/76102
dc.language.isospaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Medellínspa
dc.publisher.departmentDepartamento de Geociencias y Medo Ambientespa
dc.relation.referencesB. Petroleum, "BP Statistical Review of World Energy 2018," 2018spa
dc.relation.referencesV. Alvarado and E. Manrique, "Enhanced oil recovery: an update review," Energies, vol. 3, pp. 1529-1575, 2010.spa
dc.relation.referencesA. N. Awolayo, H. K. Sarma, and L. X. Nghiem, "Brine-Dependent Recovery Processes (Smart-Water/Low-Salinity-Water) in Carbonate and Sandstone Petroleum Reservoirs: Review of Laboratory-Field Studies, Interfacial Mechanisms and Modeling Attempts," 2018.spa
dc.relation.referencesA. A. Hamouda and O. M. Valderhaug, "Investigating enhanced oil recovery from sandstone by low-salinity water and fluid/rock interaction," Energy & Fuels, vol. 28, pp. 898-908, 2014.spa
dc.relation.referencesA. Zahid, E. H. Stenby, and A. A. Shapiro, "Improved oil recovery in chalk: wettability alteration or something else?," in Spe Europec/eage Annual Conference and Exhibition, 2010.spa
dc.relation.referencesM. Lashkarbolooki, S. Ayatollahi, and M. Riazi, "Mechanistical study of effect of ions in smart water injection into carbonate oil reservoir," Process Safety and Environmental Protection, vol. 105, pp. 361-372, 2017.spa
dc.relation.referencesN. J. Hadia, T. Hansen, M. T. Tweheyo, and O. Torsæter, "Influence of crude oil components on recovery by high and low salinity waterflooding," Energy & Fuels, vol. 26, pp. 4328-4335, 2012spa
dc.relation.referencesM. Lashkarbolooki, S. Ayatollahi, and M. Riazi, "Effect of salinity, resin, and asphaltene on the surface properties of acidic crude oil/smart water/rock system," Energy & Fuels, vol. 28, pp. 6820-6829, 2014.spa
dc.relation.referencesS. Moosavi, M. Rayhani, M. Malayeri, and M. Riazi, "Impact of monovalent and divalent cationic and anionic ions on wettability alteration of dolomite rocks," Journal of Molecular Liquids, vol. 281, pp. 9-19, 2019.spa
dc.relation.referencesR. Abhishek, A. Hamouda, and A. Ayoub, "Effect of Silica Nanoparticles on Fluid/Rock Interactions during Low Salinity Water Flooding of Chalk Reservoirs," Applied Sciences, vol. 8, p. 1093, 2018spa
dc.relation.referencesP. Jadhunandan and N. R. Morrow, "Effect of wettability on waterflood recovery for crude-oil/brine/rock systems," SPE reservoir engineering, vol. 10, pp. 40-46, 1995.spa
dc.relation.referencesN. R. Morrow, G.-q. Tang, M. Valat, and X. Xie, "Prospects of improved oil recovery related to wettability and brine composition," Journal of Petroleum science and Engineering, vol. 20, pp. 267-276, 1998.spa
dc.relation.referencesA. Lager, K. Webb, and C. Black, "Impact of brine chemistry on oil recovery," in IOR 2007-14th European Symposium on Improved Oil Recovery, 2007.spa
dc.relation.referencesK. Webb, C. Black, and H. Al-Ajeel, "Low salinity oil recovery-log-inject-log," in Middle East Oil Show, 2003.spa
dc.relation.referencesP. McGuire, J. Chatham, F. Paskvan, D. Sommer, and F. Carini, "Low salinity oil recovery: An exciting new EOR opportunity for Alaska's North Slope," in SPE Western Regional Meeting, 2005.spa
dc.relation.referencesG. G. Bernard, "Effect of floodwater salinity on recovery of oil from cores containing clays," in SPE California Regional Meeting, 1967.spa
dc.relation.referencesH. Aksulu, D. Håmsø, S. Strand, T. Puntervold, and T. Austad, "Evaluation of low-salinity enhanced oil recovery effects in sandstone: Effects of the temperature and pH gradient," Energy & Fuels, vol. 26, pp. 3497-3503, 2012spa
dc.relation.referencesN. Wardlaw and J. Cassan, "Oil recovery efficiency and the rock-pore properties of some sandstone reservoirs," Bulletin of Canadian Petroleum Geology, vol. 27, pp. 117-138, 1979spa
dc.relation.referencesS. n. Llanos, L. J. Giraldo, O. Santamaria, C. A. Franco, and F. B. Cortés, "Effect of Sodium Oleate Surfactant Concentration Grafted onto SiO2 Nanoparticles in Polymer Flooding Processes," ACS Omega, vol. 3, pp. 18673-18684, 2018spa
dc.relation.referencesD. B. Bennion, "An overview of formation damage mechanisms causing a reduction in the productivity and injectivity of oil and gas producing formations," Journal of Canadian Petroleum Technology, vol. 41, 2002spa
dc.relation.referencesJ. Stetefeld, S. A. McKenna, and T. R. Patel, "Dynamic light scattering: a practical guide and applications in biomedical sciences," Biophysical reviews, vol. 8, pp. 409-427, 2016spa
dc.relation.referencesD. López, L. J. Giraldo, J. P. Salazar, D. M. Zapata, D. C. Ortega, C. A. Franco, et al., "Metal Oxide Nanoparticles Supported on Macro-Mesoporous Aluminosilicates for Catalytic Steam Gasification of Heavy Oil Fracti ons for On-Site Upgrading," Catalysts, vol. 7, p. 319, 2017.spa
dc.relation.referencesT. Solomon, "The definition and unit of ionic strength," Journal of Chemical Education, vol. 78, p. 1691, 2001spa
dc.relation.referencesJ. D. Guzmán, S. Betancur, F. Carrasco-Marín, C. A. Franco, N. N. Nassar, and F. B. Cortés, "Importance of the adsorption method used for obtaining the nanoparticle dosage for asphaltene-related treatments," Energy & Fuels, vol. 30, pp. 2052-2059, 2016.spa
dc.relation.referencesA. Restrepo, M. Lastre, A. W. Milne, S. J. Penaloza, and E. Castro, "Effective kaolinite damage control under unfavorable chemical environment: field case," in SPE International Symposium and Exhibition on Formation Damage Control, 2012.spa
dc.relation.referencesR. Kagel and R. Nyguist, "Infrared Spectra of Inorganic Compounds," Chemical Physics Research Laboratory. The dow Chemical Company. ed: Academic Press, Inc, 1971.spa
dc.relation.referencesL. A. Prado, M. Sriyai, M. Ghislandi, A. Barros-Timmons, and K. Schulte, "Surface modification of alumina nanoparticles with silane coupling agents," Journal of the Brazilian Chemical Society, vol. 21, pp. 2238-2245, 2010.spa
dc.relation.referencesC.-L. Chang and H. S. Fogler, "Stabilization of asphaltenes in aliphatic solvents using alkylbenzene-derived amphiphiles. 1. Effect of the chemical structure of amphiphiles on asphaltene stabilization," Langmuir, vol. 10, pp. 1749-1757, 1994spa
dc.relation.referencesY. Mikami, Y. Liang, T. Matsuoka, and E. S. Boek, "Molecular dynamics simulations of asphaltenes at the oil–water interface: from nanoaggregation to thin-film formation," Energy & Fuels, vol. 27, pp. 1838-1845, 2013.spa
dc.relation.referencesJ. Giraldo, P. Benjumea, S. Lopera, F. B. Cortés, and M. A. Ruiz, "Wettability alteration of sandstone cores by alumina-based nanofluids," Energy & Fuels, vol. 27, pp. 3659-3665, 2013.spa
dc.relation.referencesA. Roustaei, S. Saffarzadeh, and M. Mohammadi, "An evaluation of modified silica nanoparticles’ efficiency in enhancing oil recovery of light and intermediate oil reservoirs," Egyptian Journal of Petroleum, vol. 22, pp. 427- 433, 2013.spa
dc.rightsDerechos reservados - Universidad Nacional de Colombiaspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial 4.0 Internacionalspa
dc.rights.spaAcceso abiertospa
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/spa
dc.subject.ddc330 - Economía::333 - Economía de la tierra y de la energíaspa
dc.subject.proposalAsfaltenosspa
dc.subject.proposalResinasspa
dc.subject.proposalAcidos nafténicosspa
dc.subject.proposalInjection of watereng
dc.subject.proposallow salinityeng
dc.subject.proposalSmartwatereng
dc.subject.proposalIonseng
dc.subject.proposalEnhanced oil recoveryeng
dc.subject.proposalNanoparticleseng
dc.titleMejoramiento de la inyección de agua de baja salinidad mediante nanopartículas aplicado al recobro mejorado de petróleospa
dc.typeReportespa
dc.type.coarhttp://purl.org/coar/resource_type/c_93fcspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/reportspa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTCASOspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa

Archivos

Bloque original

Mostrando 1 - 1 de 1
Cargando...
Miniatura
Nombre:
1017224287.2019.pdf
Tamaño:
2.31 MB
Formato:
Adobe Portable Document Format
Descripción:
Tesis de Maestría en Medio Ambiente y Desarrollo

Bloque de licencias

Mostrando 1 - 1 de 1
Cargando...
Miniatura
Nombre:
license.txt
Tamaño:
3.9 KB
Formato:
Item-specific license agreed upon to submission
Descripción: