Evaluación del uso de tetra(pentil)resorcin[4]areno mono-diazotado como Quimiosensor de ion cúprico en solución

Vista sencilla de ítem
dc.contributor.advisorMaldonado Villamil, Mauriciospa
dc.contributor.authorLópez Meza, Mónica Alexandraspa
dc.contributor.researchgroupAplicaciones Analíticas de Compuestos Orgánicos (Aaco)spa
dc.date.accessioned2024-06-18T22:55:42Z
dc.date.available2024-06-18T22:55:42Z
dc.date.issued2024-06-14
dc.descriptionilustraciones, diagramasspa
dc.description.abstractEn el presente trabajo se sintetizó y caracterizó el tetra(pentil)resorcin[4]areno que posteriormente fue monodiazotado con la sal de diazonio del ácido p-aminobenzoico y caracterizado mediante FT-IR, RMN-1H y RMN-13C. La interacción entre el ion cúprico y la resorcin[4]areno monodiazotado se estudió en agua mediante espectroscopia UV-vis. El máximo de absorción del resorcin[4]areno monodiazotado (420 nm) muestra un gran desplazamiento batocrómico hacia el rojo en presencia de Cu+2 (720 nm) y el cambio de color se observa fácilmente a simple vista. Se sugiere una explicación plausible para este comportamiento en la formación de un complejo de tipo Host-Guest y el comportamiento dinámico del macrociclo de conformación corona en solución. Los ensayos de control revelaron que el resorcin[4]areno monodiazotado tiene una respuesta altamente selectiva al ion cúprico, cualitativa y cuantitativamente. (Texto tomado de la fuente).spa
dc.description.abstractIn the present work, tetra(pentyl)resorcin[4]arene was synthesized and characterized, which was subsequently monodiazotated with the diazonium salt of p-aminobenzoic acid and characterized by FT-IR, 1H-NMR and 13C-NMR. The complexation between cupric ion and monodiazotated resorcin[4]arene was studied in water by UV-vis spectroscopy. The absorption maximum of modified resorcin[4]arene (420 nm) shows a large bathochromic red shift in the presence of Cu2+ (720 nm) and the color change is very easily observed with the naked eye. A plausible explanation for this behavior is suggested in the formation of a Host-Guest type complex and the dynamic behavior of the crown conformation macrocycle in solution. Control assays revealed that monodiazotated resorcin[4]arene has a highly selective response to cupric ion, qualitatively and quantitatively.eng
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ciencias - Químicaspa
dc.description.researchareaQuímica orgánica y analíticaspa
dc.format.extentxviii, 103 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/86264
dc.language.isospaspa
dc.publisherUniversidad Nacional de Colombiaspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Cienciasspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ciencias - Maestría en Ciencias - Químicaspa
dc.relation.references1. Hsu, C.-J., Xiao, Y.-Z., Chung, A., Hsi, H.-C., Novel applications of vacuum distillation for heavy metals removal from wastewater, copper nitrate hydroxide recovery, and copper sulfide impregnated activated carbon synthesis for gaseous mercury adsorption, Science of the Total Environment, 2023, 855,158870.spa
dc.relation.references2. Hayati, A., Umami, R.D., Wanguyun, A.P.,Putra, P., Taufiq, A.P., Supriyanto, A.,Toxicity effect of copper on histopathology of oreochromis niloticus liver with diet of lactic acid bacteria, Ecology Environment and Conservation, 2020, pp. S86–S90.spa
dc.relation.references3. Chiou, W.-Y., Hsu, F.-C., Copper toxicity and prediction models of copper content in leafy vegetables, Sustainability (Switzerland), 2019, 11(22), 6215.spa
dc.relation.references4. Fanni, D., Fanos, V., Gerosa, C., Piras, M.,Dessi, A.,Atzei, A.,Eyken, P., Gibo, Y., Faa, G., Effects of iron and copper overload on the human liver: An ultrastructural study, Current Medicinal, 2015, 21(33), pp.3768–3774.spa
dc.relation.references5. Hadjipanagiotou, C., Christou, A., Zissimos, A.M., Chatzitheodoridis, E., Varnavas, S.P., Contamination of stream waters, sediments, and agricultural soil in the surroundings of an abandoned copper mine by potentially toxic elements and associated environmental and potential human health–derived risks: a case study from Agrokipia, Cyprus, Environmental Science and Pollution Research, 2020, 27(33), pp. 41279–41298.spa
dc.relation.references6. Hussain, M.I., Naeem, M., Khan, Z.I., Naeen, M.,Akhtar, S.,Ahmad, K., Vicente, O., Yang, H.-H., Cadmium (Cd) and Copper (Cu) Exposure and Bioaccumulation Arrays in Farm Ruminants: Impact of Forage Ecotypes, Ecological Sites and Body Organs, Sustainability (Switzerland), 2022, 14(19),12595.spa
dc.relation.references7. Latif, F., Iqbal, R., Ambreen, F., Kousar, S., Ahmed, T., Aziz, S., Studies on bioaccumulation patterns, biochemical and genotoxic effects of copper on freshwater fish, Catla catla: An in vivo analysis, Brazilian J. of Biology, 2024, 84, e256905.spa
dc.relation.references8. Trung, L.G., Subedi, S., Dahal, B.,Truon, P.,Gwag, J.S., Tran, N.T., Nguyen, M.K., Highly efficient fluorescent probes from chitosan-based amino-functional carbon dots for the selective detection of Cu2+ traces, Materials Chemistry and Physics, 2022, 126772.spa
dc.relation.references9. Liu, K., Chen, K.S., Sen, D., Yu, H.-Z., Ultrasensitive detection of total copper with an electrochemical biosensor built on the in cis coupling of hexynyl CLICK-17 DNAzyme with azido self-assembled monolayers, Electrochimica Acta, 2021, 379,138125.spa
dc.relation.references10. Xiangjin Huang, Jianwen Li, Chunsheng Xie, Huasheng Zhang, Shoulian Wei, Wenfeng Lai, Shaoling Xian & Sicong Huang, A novel electrochemical sensor based on PVP–Co(OH)2 nanocomposite for the sensitive detection of Cu(II) ions, Ionics, 2021.spa
dc.relation.references11. Wu, S., Cheng, W., Li, Z.,Luo, F.,Guo,L. , Qiu, B., Lin, Z., Determination of copper ions in herbal medicine based on click chemistry using an electronic balance as a readout, Analytical Methods, 2020, 12(36), pp. 4473-4478.spa
dc.relation.references12. Castillo-Aguirre, A., Esteso, M. A., & Maldonado, M., Resorcin [4] arenes: Generalities and their role in the modification and detection of amino acids., Current Organic Chemistry, 2020, 24(21), 2412-2425.spa
dc.relation.references13. Jain, V.K.; Kanaiya, P.H. Chemistry of calix[4]resorcinarenes., Russ. Chem.Rev., 2011, 80, 75-102.spa
dc.relation.references14. Högberg, A.G. Two stereoisomeric macrocyclic resorcinol-acetaldehyde condensation products, J. Org. Chem., 1980, 45, 4498-4500.spa
dc.relation.references15. Egberink, R.J.M.; Cobben, P.L.H.M.; Vverboom, W.; Harkema, S.; Reinhoudt,D.N. Högberg compounds with a functionalized box-like cavity., J.Incl. Phenom. Mol. Recognit. Chem., 1992, 12, 151-158.spa
dc.relation.references16. Tunstad, L.M.; Tucker, J.A.; Dalcanale, E.; Weiser, J.; Bryant, J.A.;Sherman, J.C.; Helgeson, R.C.; Knobler, C.B.; Cram, D.J. Host-guest com plexation. 48. Octol building blocks for cavitands and carcerands., J. Org.Chem., 1989, 54, 1305-1312.spa
dc.relation.references17. Ryzhkina, I.S.; Kudryavtseva, L.A.; Enikeev, K.M.; Babkina, Y.A.; Konovalov,A.I.; Zuev, Y.F.; Zakharchenko, N.L. Reactivity of amphiphilic calix[4]resorcinolarenes and phenols in the reverse micellar system sodium bis(2-ethylhexyl) sulfosuccinate-decane-water., Russ. J. Gen. Chem., 2002,72, 1401-1405.spa
dc.relation.references18. Yanagihara, R.; Tominaga, M.; Aoyamal, Y. Chiral Host-Guest Interaction.A Water-Soluble Calix[l]resorcarene Having L-Proline Moieties as a Non-Lanthanide Chiral NMR Shift Reagent for Chiral Aromatic Guests in Water, J. Org. Chem., 1994, 59, 6865-6867.spa
dc.relation.references19. Schneider, U.; Schneider, H-J. Synthese und eigenschaften von makrocyclen aus resorcinen sowie von entsprechenden derivaten und wirt-gastkomplexen. Chem. Ber., 1994, 127, 2455-2469.spa
dc.relation.references20. Yamakawa, Y.; Ueda, M.; Nagahata, R.; Takeuchi, K.; Asai, M. Rapid synthesis of dendrimers based on calix[4]resorcinarenos, J. Chem. Soc., 1998, 4135–4139.spa
dc.relation.references21. Ruderisch, A.; Iwanek, W.; Pfeiffer, J.; Fischer, G.; Albert, K.; Schurig, V. Synthesis and characterization of a novel resorcinarene-based stationary phase bearing polar headgroups for use in reversed-phase high-performance liquid chromatography, J. Chromatogr., 2005, 1095, 40–49.spa
dc.relation.references22. Pietraszkiewicz, O.; Pietraszkiewicz, M. Separation of pyrimidine bases on HPLC stationary RP-18 phase coated with calix[4]resorcinareno, J. Incl. Phenom. Macrocycl. Chem., 1999, 35 (1–2), 261–270.spa
dc.relation.references23. Sokolieβ, T.; Menyes, U.; Roth, U.; Jira, T. Separation of cis- and trans-isomers of thioxanthene and dibenz[b,e]oxepin derivatives on calixarene- and resorcinarene-bonded high-performance liquid chromatography stationary phases, J. Chromatogr. A, 2002, 948, 309–319spa
dc.relation.references24. Matiz, C., síntesis verde y uso de c-tetra(aril)calix[4]resorcinarenos en la fisisorción de un monolito con base en estireno y evaluación en la microextracción por sorción en disco rotatorio (rdse) de norepinefrina,Universidad Nacional de Colombia,Colombia,2023,Recuperado a partir de: https://repositorio.unal.edu.co/bitstream/handle/unal/84519/1010203243.2023.pdf?sequence=4&isAllowed=yspa
dc.relation.references25. Jain, V. K.; Kanaiya, P. H., Chemistry of calix [4] resorcinarenos, Russ. Chem. Rev. 2011, 80 (1), 75–102.spa
dc.relation.references26. Sarmiento, R., Reacción de sulfometilación de resorcinarenos alquilados en el borde inferior y estudio del efecto de estos sustituyentes en el proceso de reconocimiento molecular de colina,2018,Recuperado a partir de: https://repositorio.unal.edu.co/bitstream/handle/unal/64729/Tesis%20Maestria%20Roger%20Sarmiento%20forero%20%28version%20final%29.pdf?sequence=1&isAllowed=y.spa
dc.relation.references27. Timmerman, P., Verboom,W., Reinhoudt,D.N., Resorcinarenes, Tetrahedron,1996, 52-2663.spa
dc.relation.references28. Hoegberg, A. G. S., Synthetic and Structural Studies of Calix[4]pyrogallolarenes Towards Biological Applications, J. Am. Chem. Soc.,1980, 102 6046-6050.spa
dc.relation.references29. Hoegberg, A.G.S., Two stereoisomeric macrocyclic resorcinol-acetaldehyde condensation products, J. Org. Chem.,1980,45 4498.spa
dc.relation.references30. Moore, D.; Watson, G.W.; Gunnlaugsson, T.; Matthews, S.E. Selective formation of the rctt chair stereoisomers of octa-O-alkyl resorcin[4]arenes using Brønsted acid catalysis., New J. Chem., 2008, 32, 994-1002.spa
dc.relation.references31. Fransen, J.R.; Dutton, P.J.,Cation binding and conformation of octafunctionalized calix[4]resorcinarenes., Can. J. Chem., 1995, 73, 2217-2223.spa
dc.relation.references32. Volkmer, D.; Fricke, M.; Mattay, J. Interfacial electrostatics guiding the crystallization of CaCO3 underneath monolayers of calixarenes and resorcarenes, J. Mater. Chem., 2004, 14, 2249-2259.spa
dc.relation.references33. Mironova, D.A.; Muslinkina, L.A.; Syakaev, V.V.; Morozova, J.E.; Yanilkin, V.V.; Konovalov, A.I.; Kazakova, E.Kh. Crystal violet dye in complexes with amphiphilic anionic calix[4]resorcinarenes: binding by aggregates and individual molecules, J. Colloid Interface Sci., 2013, 407, 148-154.spa
dc.relation.references34. Hayashida, O.; Mizuki, K.; Akagi, K.; Matsuo, A.; Kanamori, T.; Nakai, T.;Sando, S.; Aoyama, Y. Macrocyclic glycoclusters. Self-aggregation and phosphate-induced agglutination behaviors of calix[4]resorcarene-based quadruple-chain amphiphiles with a huge oligosaccharide pool., J. Am. Chem.Soc., 2003, 125(2), 594-601.spa
dc.relation.references35. Forero R., Reacción de sulfometilación de resorcinarenos alquilados en el borde inferior y estudio del efecto de estos sustituyentes en el proceso de reconocimiento molecular de colina, U. Na. de C.,2018.spa
dc.relation.references36. Salorinne, K.; Lopez-Acevedo, O.; Nauha, E.; H€akkinen, H.; Nissinen, M., Solvent driven formation of silver embedded resorcinarene nanorods, Cryst. Eng. Comm., 2012, 14, 347-350.spa
dc.relation.references37. Castillo-aguirre, A.; Rivera-monroy, Z.; Maldonado, M., Selective O-Alkylation of the Crown Conformer of Tetra(4 -hydroxyphenyl)calix[4]resorcinarene to the Corresponding Tetraalkyl Ether, Molecules,2017, 22(10),1660.spa
dc.relation.references38. Velásquez-Silva, A.; Cortés, B.; Rivera-Monroy, Z.; Pérez-Redondo, A.; Maldonado, M.,Crystal structure and dynamic NMR studies of octaacetyltetra(propyl)calix[4]resorcinarene.,J. Mol. Struct., 2017, 1137, 380-386.spa
dc.relation.references39. Casas-Hinestroza, J.L.; Maldonado, M. Conformational Aspects of the Oacetylation of C-tetra(phenyl)calixpyrogallol[4]arene., Molecules, 2018,23(5), 1-9.spa
dc.relation.references40. Straub,C., Falàbu, T., Paulus, Schmidt.,S C., Wegelius, E.F., Kolehmainen, E.,Bohmer,V.,Rissanen, K., Vogt, W., ,Selective Derivatisation of Resorcarenes – 6. Mannich Reaction with Amino Alcohols Schmidt, European J. Org. Chem., 2000, 3937–3944.spa
dc.relation.references41. Sanabria, E.; Esteso, M. Á.; Pérez-redondo, A.; Vargas, E.; Maldonado, M., Synthesis and Characterization of Two Sulfonated Resorcinarenes: A New Example of a Linear Array of Sodium Centers and Macrocycles, Molecules, 2015, 20, 9915–9928.spa
dc.relation.references42. Maldonado, M., Sanabria, E., Batanero, B., Esteso, M.Á., Apparent molal volume and viscosity values for a new synthesized diazoted resorcin[4]arene in DMSO at several temperatures, Journal of Molecular Liquids, 2017, 231, pp. 142-148.spa
dc.relation.references43. L. Abd-Alredha, R. Al-Rubaie, R. Jameel Mhessn, Synthesis and characterization of Azo dye Para red and new derivatives, E-J. Chem. 9,2012, 465–470.spa
dc.relation.references44. Heinrich Z, Color Chemistry, Syntheses, properties and applications of organic dyes and pigments, VCH, 1991, 496.spa
dc.relation.references45. Brown, D., Laboureur, P., The aerobic biodegradability of primary aromatic amines, Chemosphere, 1983, 12(3), 405.spa
dc.relation.references46. Paraneswari N, Muthakrishnan J and Guanasekaran P., Synthesis and Characterization of Azo Dye Para Red and New Derivatives, Indian J. Exp. Biol., 2006, 44, 618.spa
dc.relation.references47. Maldonado, M., Sanabria, E., Velasquez-Silva, A., Casas-Hinestroza, J.L., Esteso, M.A. Comparative study of the volumetric properties of three regioisomers of diazoted C-tetra(propyl)resorcin[4]arene in DMSO at various temperatures, Journal of Molecular Liquids, 2021, 325,115252.spa
dc.relation.references48. Li, N., Harrison, R.G., Lamb, J.D., Application of resorcinarene derivatives in chemical separations, J. of Inclusion Phenomena and Macrocyclic Chemistry,2014, 78(1-4), pp. 39–60.spa
dc.relation.references49. Daniel Pedro-Hernández, L., Hernández-Montalbán, C., Martínez-Klimova, E., Ramírez-Ápan, T., Martínez-García, M., Synthesis and anticancer activity of open-resorcinarene conjugates, Bioorganic and Medicinal Chemistry Letters, 2020, 30(14), 127275.spa
dc.relation.references50. Al-Mahadeen, M.M., Jiries, A.G., Al-Trawneh, S.A., ...Eldouhaibi, A.S., Sagadevan, S, Kinetics and equilibrium studies for the removal of heavy metal ions from aqueous solution using the synthesized C-4 bromophenylcalix[4]resorcinarene adsorbent, Chemical Physics Letters, 2021, 783, 139053.spa
dc.relation.references51. Shaban, A., Eddaif, L., Comparative Study of a Sensing Platform via Functionalized Calix[4]resorcinarene Ionophores on QCM Resonator as Sensing Materials for Detection of Heavy Metal Ions in Aqueous Environments, Electroanalysis, 2021, 33(2), pp. 336–346.spa
dc.relation.references52. Ngurah, B.I.G.M., Heavy Metal Cations Adsorption by Cinnamoyl C-methylcalix [4] Resorcinarene, Journal of Physics: Conference Series, 2020.spa
dc.relation.references53. Eddaif, L., Shaban, A., Szendro, I., Calix[4]Resorcinarene Macrocycles Interactions with Cd2+, Hg2+, Pb2+, and Cu2+ Cations: A QCM-I and Langmuir Ultra-thin Monolayers Study, Electroanalysis, 2020, 32(4), pp. 755–766.spa
dc.relation.references54. Eddaif, L., Shaban, A., Telegdi, J., Szendro, I., A piezogravimetric sensor platform for sensitive detection of lead (II) ions in water based on calix[4]resorcinarene macrocycles: Synthesis, characterization and detection, Arabian Journal of Chemistry, 2020, 13(2), pp. 4448–4461.spa
dc.relation.references55. M A Sarmentero, P Ballester , Recognition of Guests by Water-Stabilized Cavitand Hosts, Org. Lett.,2006, 8 3477 .spa
dc.relation.references56. Hayashida,O.,Uchiyama,M., Multivalent Macrocyclic Hosts:  Histone Surface Recognition, Guest Binding, and Delivery by Cyclophane-Based Resorcinarene Oligomers, J. Org. Chem.,2007, 72 610 .spa
dc.relation.references57. Hayashida,O.,Ogawa,N.,Uchiyama,M.,Surface Recognition and Fluorescence Sensing of Histone by Dansyl-Appended Cyclophane-Based Resorcinarene Trimer, J. Am. Chem. Soc.,2007, 129 ,13698.spa
dc.relation.references58. Liu, JL., Sun, M., Shi, YH. et al. Functional modification, self-assembly and application of calix[4]resorcinarenes., J. Incl. Phenom Macrocycl. Chem.,2022,102, 201–233.spa
dc.relation.references59. Kashapov, R.R., Razuvayeva, Y.S., Ziganshina, A.Y., ...Kadirov, M.K., Zakharova, L.Y., N-Methyl-d-glucamine–Calix[4]resorcinarene Conjugates: Self-assembly and biological properties, Molecules, 2019, 24(10)-1939.spa
dc.relation.references60. Ermakova, A.M., Morozova, J.E., Shalaeva, Y.V., ...Antipin, I.S., Konovalov, A.I., The supramolecular approach to the phase transfer of carboxylic calixresorcinarene-capped silver nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2017, 524, pp. 127–134.spa
dc.relation.references61. Delangle, P., Dutasta, J.-P., Tetraphosphonate-calix[4]resorcinarene. A powerful host for alkali metal and ammonium cations encapsulation, Tetrahedron Letters, 1995, 36(51), pp. 9325-9328.spa
dc.relation.references62. Arnott, G., Hunter, R.,Su,H., Synthesis and characterization of chiral, bridged resorcinarenes as templates for asymmetric catalysis, Tetrahedron,2006, 62 -977.spa
dc.relation.references63. Shirakawa, S., Shimizu S., Dehydrative Amination of Alcohols in Water Using a Water-Soluble Calix[4]resorcinarene Sulfonic Acid, Synlett,2008, 1539-1542.spa
dc.relation.references64. İşci, Ü., Aygün, M., Sevincek, R., Zorlu, Y., Dumoulin, F., Resorcinarene-mono-benzimidazolium salts as NHC ligands for Suzuki- Miyaura cross-couplings catalysts, Turkish J. of Chemistry.,2015,39, 6.spa
dc.relation.references65. Mishra, D.R.; Darjee, S.M.; Bhatt, K.D.; Modi, K.M.; Jain, V.K. Calix protected gold nanobeacon as turn-off fluorescent sensor for phenylalanine., J. Incl. Phenom. Macrocycl. Chem., 2015, 82, 425.spa
dc.relation.references66. Shumatbaeva, A.M., Morozova, J.E., Syakaev, V.V., (...), Kadirov, M.K., Antipin, I.S.The pH-responsive calix[4]resorcinarene-mPEG conjugates bearing acylhydrazone bonds: Synthesis and study of the potential as supramolecular drug delivery systems, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020,589,124453.spa
dc.relation.references67. Priyangga, K.T.A., Kurniawan, Y.S., Yuliati, L., Synthesis and characterizations of C-3-Nitrophenylcalix[4]resorcinarene as a potential chemosensor for La(III) ions, IOP Conference Series: Materials Science and Engineering, 2020, 959 ,012014.spa
dc.relation.references68. Yang, Q., Yan, C., Zhu, X., A fluorescent chemosensor for paeonol based on tetramethoxy resorcinarene tetraoxyacetic acid, Sensors and Actuators B: Chemical, 2014, 191, 53–59.spa
dc.relation.references69. Gaynanova, G.A.; Bekmukhametova, A.M.; Mukhitova, R.K.; Kharlamov,S.V.; Ziganshina, A.Y.; Zakharova, L.Y.; Konovalov, A.I. Pyrene fluorescence quenching in supramolecular systems based on dimethylaminomethylated resorcinarene. J. Mol. Liq. J., 2015, 206, 316-320.spa
dc.relation.references70. Hulanicki, A.; Glab, S.; Ingman, F., Chemical sensors: definitions and classification, Pure Appl. Chem., 1991, 63 (9), 1247–1250.spa
dc.relation.references71. Tárraga Tómas, A., Sensores moleculares: un reto para el químico, una demanda social. Academia de Ciencias de la Región de Murcia,2012.spa
dc.relation.references72. Mirsky, V. M.; Yatsimirsky, A. K., Artificial Receptors for Chemical sensors; WILEY-VCH Verlag GmbH & Co. KGaA, 2010.spa
dc.relation.references73. Gomez Vega, P. J.; Ochoa Lara, K. L.; Corona Martínez, D. O.; Juarez, J.; Reyes Márquez, V.,Materiales Supramoleculares: Quimiosensores Y Otras Aplicaciones prácticas: Supramolecular Materials: Chemosensors and Other Practical Applications, Tecnociencia Chih., 2023, 17, e1316.spa
dc.relation.references74 . Rodriguez, I. J. B. Quimiosensores fluorescentes para nucleótidos y aniones biológicos basados en receptores dinucleares de zinc (II): síntesis y reconocimiento molecular, México, 2017.spa
dc.relation.references75. Noriega, P. Evaluación de un nuevo quimiosensor selectivo para cobre (II) mediante un estudio teórico DFT,Argentina, 2018.spa
dc.relation.references76. Shome, A., Applications of supramolecular materials in real world: a mini review. Asian J. of Chemistry,2023, 35 (2): 305-315.spa
dc.relation.references77. Uekama, K., Fujinaga, T., Hirayama, F., Otagiri, M., Yamasaki, M., Seo, H., Hashimoto, T. & Tsuruoka, M., Improvement of the oral bioavailability of digitalis glycosides by cyclodextrin complexation. J. Pharm. Sci.,1983, 72(11): 1338-1341.spa
dc.relation.references78. Narda, R., Sensor colorimétrico a base de nanopartículas de plata funcionalizadas con ácido 8-aminooctanoico para la detección de aniones en medio acuoso,México,2023.spa
dc.relation.references79. Asociación internacional de Cobre, Copper Alliance, Estados Unidos,2023,[Citado el 15 de noviembre de 2023] Recuperado a partir de:https://copperalliance.org/es/policy-focus/health-safety/human-health/.spa
dc.relation.references80. Universidad Nacional de Colombia, Periódico UNAL Medio ambiente, El cobre: un metal codiciado en el sector tecnológico, pero un enemigo del medioambiente, 5 de julio de 2023,[Citado el 10 de octubre de 2023],Recuperado a partir de:https://periodico.unal.edu.co/articulos/el-cobre-un-metal-codiciado-en-el-sector-tecnologico-pero-un-enemigo-del-medioambiente.spa
dc.relation.references81. Ranking de los principales países productores de cobre a nivel mundial en 2022, [Citado el 10 de octubre de 2023],Recuperado a partir de: https://es.statista.com/estadisticas/635359/paises-lideres-en-la-produccion-de-cobre anivelmundial/#:~:text=La%20producci%C3%B3n%20de%20cobre%20en,2%2C2%20millones%20de%20toneladas.spa
dc.relation.references82. Roca, A. & A. Guerrero,Efecto citotóxico por cobre en Allium cepa (Amaryllidaceae, Arnaldoa, 2021, 28(3),727-746.spa
dc.relation.references83. Zubillaga, M.,Arnal,N., Bellini, M. J., Efectos de sobrecargas de cobre sobre el metabolismo del colesterol, y su posible vinculación con el desarrollo de neurodegeneración de tipo alzheimer, Sedici, ,2021,7(2),346-7.spa
dc.relation.references84. Qadri, T., Ali, I., Hussain, M., Ahmed, F., Shah, R. M., and Hussain, Z., Synthesis of New Tetra Triazole Functionalized calix[4]resorcinarene and Chemosensing of Copper Ions in Aqueous Medium, Current Org. Chemistry ,2020; 24 (3), 332 – 337.spa
dc.relation.references85. Castillo-Aguirre, A.; Rivera-Monroy, Z.; Maldonado, M. Selective O-Alkylation of the Crown Conformer of Tetra(4-hydroxyphenyl)calix[4]resorcinarene to the Corresponding Tetraalkyl Ether, Molecules, 2017, 22(10), 1660.spa
dc.relation.references86. Maldonado, M.; Sanabria, E.; Batanero, B.; Esteso, M.A. Apparent molal volume and viscosity values for a new synthesized diazoted resorcin[4]arene in DMSO at several temperatures, J. Mol. Liq, ,2017, 231, 142–148.spa
dc.relation.references87. Castillo-Aguirre, A.A.; Sanabria, E.; Maldonado, M.; Esteso, M.A. DMSO-controlled self-assembly of supramolecular structures of aryl-resorcinarenes, J. Mol. Liq.,2023, 384, 122703spa
dc.relation.references88. Pineda-Castañeda, H.M.; Rivera-Monroy, Z.J.; Maldonado, M. Efficient Separation of C-Tetramethylcalix[4]resorcinarene Conformers by Means of Reversed-Phase Solid-Phase Extraction, ACS Omega, 2023, 8, 231-237.spa
dc.relation.references89. Jain, V.K.; Kanaiya, P.H.; Bhojak, N. Synthesis, Spectral Characterization of Azo Dyes Derived from Calix[4]resorcinarene and their Application in Dyeing of Fibers, Fib. Polym., 2008, 9(6), 720-726.spa
dc.relation.references90. Sheng,R., Wang,P., Liu,W., Wu,X., Wu,S., A new colorimetric chemosensor for Hg+2 based on coumarin azine derivative,Sensors and Actuators B: Chemical,2008, 128,507-511.spa
dc.relation.references91. Universidad Católica de Oriente, Prácticas de laboratorio, [Citado el 10 de octubre de 2023], recuperado a partir de https://repositorio.uco.edu.co/jspui/bitstream/20.500.13064/1653/1/Química%20general%20prácticas%20de%20laboratorio.pdf.spa
dc.relation.references92. Wright, A.J.; Matthews, S.E.; Fischer, W.B.; Beer, P.D. Novel resorcin[4]arenes as potassium-selective ion-channel and transporter mimics, Chemistry, 2001,7(16), 3474-3481.spa
dc.relation.references93. Elçin, S.; Ilhan, M.M.; Deligöz, H. Synthesis and spectral characterization of azo dyes derived from calix[4]arene and their application in dyeing of fibers.spa
dc.relation.references94.Quino, I., Ramos, O., Guisbert, E., Determinacion del límite de detección instrumental (ldi) y limite de cuantificación instrumental (lci) en elementos traza de agua subterránea, Bol. Quim.,2007,24( 1 ),53-57.spa
dc.relation.references95. Puppo, M., Cerruti, C.,Quiroga, A., Química para agronomía, Fuerzas intermoleculares y Propiedades de líquidos puros, Editorial de la universidad de La Plata, 2017, pág. 34-57.spa
dc.relation.references96. Cante, I.,Síntesis de complejos de cobre y paladio con calixarenos polimerizables,Universidad Nacional Autónoma de México, México, 2013,Recuperado a partir de: https://riubu.ubu.es/bitstream/10259/124/5/T_200.pdf.spa
dc.relation.references97.Cotton, F.A., Willkinson, G., Murillo, C.A., Bochmann, Advanced inorganic Chemistry,6a ed., Interscience Publishers,1999, pág. 864.spa
dc.relation.references98. Fombona,S., Complejos de Cobre(II): Termocrismo,Universidad de Oviedo,España,2014.Recuperado a partir de:https://digibuo.uniovi.es/dspace/bitstream/handle/10651/38412/TFG_SergioFombonaCorrionero.pdf?sequence=3&isAllowed=y.spa
dc.relation.references99.Ozutsumi, K., Kawashima, T., Structure of iron(III) and formation of iron(III) thiocyanato complexes in N,N-dimethylacetamide, Polyhedron,1993, 12(18), ,2185-2192.spa
dc.relation.references100.Carter, E., Hazeland,E.L., Murphy,D.M., Ward B.D. Structure, EPR/ENDOR and DFT characterisation of a [Cu II (en) 2](OTf) 2 complex,Dalton Transactions, 2013, 42(42), 15088-15096.spa
dc.relation.references101. Montanari, F.; Landini, D.; Rolla, F. Host Guest Complex Chemistry II,Springer,1982,101.spa
dc.relation.references102. Schneider, H.J., Schneider, U. The host-guest chemistry of resorcinarenos, J. Incl Phenom Macrocycl Chem.,1994, 19, 67–83.spa
dc.relation.references103.Podyachev,S.N.,Syakaev,V.V.,Sudakova,S.N.,Shagidullin,R.R.,Osyanina,D.V.,Awakumova,L.V.,Buzykin,B.I.,Latypov,S.K.,Bauer,I.,Habicher,W,D.,Konovalov,A.I., Chemistry of calix[4]resorcinarenes,J. Inclusion Phenom. Macrocycl. Chem.,2007, 5855.spa
dc.relation.references104.Podyachev,S.N.,Burmakina,N.E.,Syakaev,V.V.,Sudakova,S.N.,Shagidullin,R.R.,Konovalov,A.I., Tetrahedron,2009, 65- 408.spa
dc.relation.references105. Raval, J., Trivedi, R. & Prajapati, P. Preparation, Characterization, and In-Vitro Assessment of Calixarene Nanovesicles: A Supramolecular Based Nano-Carrier for Paclitaxel Drug Delivery, Pharm. Chem.,2021, J 55, 570–579.spa
dc.relation.references106. Salorinne, K., Nauha, E., Nissinen, M., Resorcinarene bis-thiacrowns: Prospective host molecules for silver encapsulation, Chemistry - An Asian Journal, 2012, 7(4), 809-817.spa
dc.relation.references107. Herrera, S., Diseño de un sistema de gestión de calidad basado en la norma ISO 15189: 2012, Área de química del laboratorio Analítica Bio Médica, Quito, 2022, Recuperado a partir de: //efaidnbmnnnibpcajpcglclefindmkaj/http://sgi.ideam.gov.co/documents/412030/35488871/M-S LCI038+INSTRUCTIVO+DE+CONFIRMACIÓN+O+VALIDACIÓN+DE+MÉTODOS+ANALÍTICOS+v3.pdf/cd82e785-16f2-4ffa-b965-4614a9808f38?version=1.0.spa
dc.relation.references108. Noriega, P.,Evaluación de un nuevo quimiosensor selectivo para cobre (II) mediante un estudio teórico DFT,2018, Recuperado de: //efaidnbmnnnibpcajpcglclefindmkaj/https://bibliotecavirtual.unl.edu.ar:8443/bitstream/handle/11185/2132/RE4.pdf?sequence=1&isAllowed=y.spa
dc.relation.references109. March, J., Advanced Organic Chemistry, 6° edición, Editorial John Wiley and sons, 1992, Canada, pp 668-672.spa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial-SinDerivadas 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/spa
dc.subject.ddc540 - Química y ciencias afines::543 - Química analíticaspa
dc.subject.ddc540 - Química y ciencias afines::547 - Química orgánicaspa
dc.subject.ddc540 - Química y ciencias afines::546 - Química inorgánicaspa
dc.subject.ddc540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesspa
dc.subject.proposalResorcinarenospa
dc.subject.proposalConformación coronaspa
dc.subject.proposalInteracción huésped-hospederospa
dc.subject.proposalResorcinareneeng
dc.subject.proposalCrown conformationeng
dc.subject.proposalHost-guest interactioneng
dc.subject.unescoQuímica experimentalspa
dc.subject.unescoExperimental chemistryeng
dc.subject.unescoCompuesto químicospa
dc.subject.unescoChemical compoundseng
dc.subject.wikidataionspa
dc.subject.wikidataioneng
dc.subject.wikidatapropiedad químicaspa
dc.subject.wikidatachemical propertyeng
dc.subject.wikidataresorcinareneeng
dc.titleEvaluación del uso de tetra(pentil)resorcin[4]areno mono-diazotado como Quimiosensor de ion cúprico en soluciónspa
dc.title.translatedEvaluation of the use of mono-diazotated tetra(pentyl)resorcin[4]arene as a cupric ion chemosensor in solutioneng
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentEstudiantesspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
dcterms.audience.professionaldevelopmentMaestrosspa
dcterms.audience.professionaldevelopmentPúblico generalspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.fundernameUniversidad Nacional de Colombiaspa

Archivos

Bloque original

Mostrando 1 - 1 de 1
Miniatura
Nombre:
1023914199.2024.pdf
Tamaño:
4.34 MB
Formato:
Adobe Portable Document Format
Descripción:
Tesis de Maestría en Ciencias - Química
Descargar

Bloque de licencias

Mostrando 1 - 1 de 1
Miniatura
Nombre:
license.txt
Tamaño:
5.74 KB
Formato:
Item-specific license agreed upon to submission
Descripción:
Descargar

Colecciones

Maestría en Ciencias - Química