Ni-Ce immobilized catalysts in cordierite monoliths for dry reforming of methane

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dc.contributor.advisorDaza Velásquez, Carlos Enrique
dc.contributor.authorOsorio Zabala, María Alejandra
dc.contributor.researchgroupEstado Sólido y Catálisis Ambientalspa
dc.date.accessioned2023-12-07T15:46:43Z
dc.date.available2023-12-07T15:46:43Z
dc.date.issued2023-12-05
dc.descriptionilustraciones, fotografíasspa
dc.description.abstractEn esta tesis de maestría, catalizadores tipo óxido mixto de Ni-Mg-Al promovidos con Ce (1-6%) inmovilizados y en polvo de se obtuvieron mediante el método de coprecipitación y recubrimiento en suspensión de precursores tipo hidrotalcita. Se estudió el comportamiento de los materiales en el reformado en seco de metano, teniendo en cuenta el papel promotor del Ce y el efecto de la inmovilizar de los óxidos mixtos en monolitos de cordierita sobre las propiedades fisicoquímicas del catalizador. Los catalizadores se caracterizaron por diversas técnicas analíticas para evaluar su composición química, propiedades térmicas, estructurales, reductivas, básicas y morfológicas. La evaluación catalítica se estudió mediante varias pruebas de estabilidad durante 8h a 700 °C (para catalizadores no reducidos) y a 600 °C (para catalizadores prereducidos) con valores WHSV de 94,680 y de 23.670 mL·gCat-1·h-1. (Texto tomado de la fuente)
dc.description.abstractIn this master’s thesis, Ni-Mg-Al powdered and immobilized mixed oxide-type catalysts promoted with Ce (1-6%) were obtained by the method of coprecipitation and slurry coating of hydrotalcite precursors. The promoter role of the Ce and the effect of immobilizing the mixed oxides in cordierite monoliths on the physicochemical properties and the catalytic performance of the materials in the dry reforming of methane were studied. The catalysts were characterized by diverse analytical techniques to evaluate their chemical composition, thermal and structural properties, and reductive, basic, and morphological properties. The catalytic evaluation was studied through several stability tests for 8h at 700 ° C (for non-reduced catalysts) and at 600 °C (for pre-reduced catalysts) with WHSV of 94,680 and 23,670 mL·gCat -1·h-1.
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Ciencias - Químicaspa
dc.description.researchareaCatalizadores para el reformado seco de metanospa
dc.format.extent90 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.identifier.instnameUniversidad Nacional de Colombiaspa
dc.identifier.reponameRepositorio Institucional Universidad Nacional de Colombiaspa
dc.identifier.repourlhttps://repositorio.unal.edu.co/spa
dc.identifier.urihttps://repositorio.unal.edu.co/handle/unal/85052
dc.language.isoengspa
dc.publisher.branchUniversidad Nacional de Colombia - Sede Bogotáspa
dc.publisher.facultyFacultad de Cienciasspa
dc.publisher.placeBogotá, Colombiaspa
dc.publisher.programBogotá - Ciencias - Maestría en Ciencias - Químicaspa
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dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.licenseAtribución-NoComercial 4.0 Internacionalspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/spa
dc.subject.ddc540 - Química y ciencias afines::546 - Química inorgánicaspa
dc.subject.ddc540 - Química y ciencias afines::542 - Técnicas, procedimientos, aparatos, equipos, materialesspa
dc.subject.lembCatalizadoresspa
dc.subject.lembCatalystseng
dc.subject.lembInhibidores químicosspa
dc.subject.lembChemical inhibitorseng
dc.subject.proposalSynthesis gasspa
dc.subject.proposalReformingeng
dc.subject.proposalMethaneeng
dc.subject.proposalMixed oxideseng
dc.subject.proposalMonolitheng
dc.subject.proposalGreenhouse effecteng
dc.subject.proposalGas de síntesisspa
dc.subject.proposalReformadospa
dc.subject.proposalMetanospa
dc.subject.proposalÓxidos mixtosspa
dc.subject.proposalMonolitospa
dc.subject.proposalEfectivo invernaderospa
dc.titleNi-Ce immobilized catalysts in cordierite monoliths for dry reforming of methane
dc.title.translatedCatalizadores de Ni-Ce inmovilizados en monolitos de cordierita para el reformado seco de metano
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_ab4af688f83e57aaspa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttp://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/acceptedVersionspa
dcterms.audience.professionaldevelopmentEstudiantesspa
dcterms.audience.professionaldevelopmentInvestigadoresspa
dcterms.audience.professionaldevelopmentMaestrosspa
dcterms.audience.professionaldevelopmentPúblico generalspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.awardtitleCatalizadores de Ni a partir de hidrotalcitas inmovilizadas en monolitos para la transformación de gases de efecto invernaderospa

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