Estudio de las propiedades biofuncionales del camu-camu (Myrciaria dubia (Kunth) McVaugh) y aplicación en un producto alimenticio

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Autores

García Chacón, Juliana María

Director

Osorio Roa, Coralia

Tipo de contenido

Trabajo de grado - Doctorado

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Español

Fecha de publicación

2023-06

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Abstract

This thesis presents the study of the sensory and biofunctional properties of the camu-camu fruit (Myrciaria dubia) from the Colombian Amazon. The aroma of the fruit was studied in a volatile extract obtained using the SAFE (Solvent Assisted Flavor Evaporation) technique, which was analyzed by GC-O (gas chromatography coupled to olfactometry) and by GC-MS (gas chromatography coupled to mass spectrometry), identifying four olfactory active compounds in the aroma of this fruit: isoamyl acetate,  -pinene, limonene and  -caryophyllene. Subsequently, the inhibition of the ACE-1 enzyme (antihypertensive activity) and of -amylase and -glucosidase was evaluated, finding that the antihyperglycemic activity of this fruit was quite promising. Therefore, a successive partitioning of the polar extract of the fruit (pulp and peel) was carried out with solvents of increasing polarity (pentane, dichloromethane, ethyl acetate, butanol, and water). From bioguided fractionation, and HPLC-MS analysis, (S)-4-butoxy-2-hydroxy-4-oxo-butanoic acid and (S)-4-butoxy-3- hydroxy-4- oxo-butanoic were isolated and identified, as potent inhibitors of -amylase and -glucosidase. The use of molecular-docking tools demonstrated that the antihyperglycemic activity of fruit malic acid was enhanced by the presence of alkyl groups in the corresponding esters. Different powders were obtained from the fruit by lyophilization and by spray-drying. In the microencapsulation process, a 3x2 experimental design was used with three types of encapsulating agent (maltodextrin, whey protein, and a 1:1 mixture of both) and two inlet temperatures (150 and 180 C). The physicochemical, morphological and biofunctional characterization of the solids was carried out. Based on the content of bioactive compounds (anthocyanins, ascorbic acid, and malic acid), three solids were selected to be incorporated into two types of beverages (a yogurt and white grape juice) that were subjected to sensory evaluation. The study of the bioaccessibility of camu-camu powders using the static model of gastrointestinal digestion in vitro, showed a greater retention of bioactive compounds, and an adequate release of the compounds in the gastrointestinal tract. Thus, it was concluded that the dehydration processes allow to increase the fruit shelf-life and preserve its biofunctional properties.

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